Multi-analyte method for the quantification of bisphenol related compounds in canned food samples and exposure assessment of the Spanish adult population

Lestido‐Cardama, Antía; Sendón, Raquel; Bustos, Juana; Santillana, M. I.; Losada, Perfecto Paseiro; Quirós, Ana Rodríguez Bernaldo de

doi:10.1016/j.fpsl.2021.100671

Cited by 27 publications

(13 citation statements)

References 32 publications

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“…This model allows the exposure assessment of migrants by using information on packaging (use, composition), consumption data, and so on (Oldring et al., 2014). Dietary exposure can also be assessed more realistic by combining data on food consumption obtained from consumer surveys and the migrated substance concentration (Lestido‐Cardama, Vázquez‐Loureiro et al., 2021; Lestido‐Cardama, Sendón et al., 2021).…”

Section: Dietary Exposure Assessmentmentioning

confidence: 99%

“…Beverages and aqueous and acid foods turned out to be the foodstuffs with the great contribution to the exposure due to the high consumption of these products. More recently, Lestido‐Cardama et al., reported a study on the dietary exposure of the Spanish adult population to bisphenol‐related compounds migrating from metal food and beverage cans (Lestido‐Cardama, Vázquez‐Loureiro et al., 2021; Lestido‐Cardama, Sendón et al., 2021). The estimated exposure levels were also below the TDIs.…”

Section: Dietary Exposure Assessmentmentioning

confidence: 99%

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Food and beverage can coatings: A review on chemical analysis, migration, and risk assessment

Lestido‐Cardama

Sendón

Bustos

et al. 2022

Comp Rev Food Sci Food Safe

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The internal surface of food and beverage cans is generally covered with polymeric coatings to preserve food and protect metal substrate from corrosion.Coating materials are complex formulations that contain different starting substances (e.g., monomers, prepolymers, additives, etc.) and in addition during the manufacture of the material several compounds can be formed (e.g., reaction products, degradation products, etc.). These substances have the potential to migrate into the food. Many of them have not been identified and only some have been toxicologically evaluated. This article aims to provide a comprehensive review on the analytical methods used for the identification of potential migrants in can coatings. The migration and exposure to chemicals migrating from can coatings are also reviewed and discussed so far, which is essential for risk assessment. Moreover, a brief section on the current status of the legislation on varnishes and coatings for food contact in Europe is also presented. Liquid chromatography coupled to diode array and fluorescence detectors and particularly to mass spectrometry and gas chromatography-tandem mass spectrometry seem to be the techniques of choice for the identification of potential migrants in can coatings. Some studies have reported migration levels of BPA (bisphenol A) and BADGE (bisphenol A diglycidyl ether) and derivatives exceeding the specific migration limits set in the European legislation. On the whole, low dietary exposure to migrants from can coatings has been reported. However, it is interesting to highlight that in these studies the combined exposure to multiple chemicals has not been considered.

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Section: Dietary Exposure Assessmentmentioning

confidence: 99%

Section: Dietary Exposure Assessmentmentioning

confidence: 99%

Food and beverage can coatings: A review on chemical analysis, migration, and risk assessment

Lestido‐Cardama

Sendón

Bustos

et al. 2022

Comp Rev Food Sci Food Safe

Self Cite

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show abstract

“…Various methods to detect and quantify the presence of these compounds in food products have been deployed based on chromatographic and mass spectrometric techniques. [13][14][15][16][17][18][19] Among numerous BPA derivatives, the so-called cyclo-di-BADGE or cyclo-diBA is an interesting but elusive chemical. As illustrated in Fig.…”

Section: Introductionmentioning

confidence: 99%

“…So far, there has been no comprehensive characterization made on cyclo-di-BADGE as a chemical of interest. It is worth noting that except some mass spectrometric and chromatographic analyses, [19][20][21][22][23] the molecular structural and solid-state properties of cyclo-di-BADGE are completely missing in the existing literature. The lack of sufficient characterization for cyclo-di-BADGE is somewhat surprising to us, given that it is only a medium-size organic compound without a very high degree of structural complexity.…”

Section: Introductionmentioning

confidence: 99%

“…It is worth mentioning that separation of the two diastereomers of cyclo-di-BADGE was previously achieved by using an HPLC system. 19,23 A starting point of solving this challenging problem was based on a serendipitous discovery recently made in our lab. In an attempt to recrystallize certain pyrenedione-derived organic chromophores, a few pieces of colorless single crystals were collected and then identified as cyclo-di-BADGE by singlecrystal X-ray diffraction (XRD) analysis.…”

Section: Introductionmentioning

confidence: 99%

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