This paper presents a fast and rigorous design method for grating-based metal-free polarizing filter applications using two-step hybrid optimization techniques. Grating structures utilizing the total internal reflection in a lamellar configuration were used to achieve metal-free solution, which is a key technology in the chirped pulse amplification for high power laser system. Here two polarizing filters were designed: polarization sensitive and polarization insensitive. Those polarization performances were characterized by the rigorous coupled-wave analysis (RCWA), and the design parameters of grating structures, pitch, depth, and filling factor were optimized by two-step hybrid optimization procedure because the diffraction characteristics of grating-based polarizing filters are highly sensitive to small changes in design parameters. The Taguchi method is incorporated into selection process in the genetic algorithm, which indicates that the Taguchi method optimizes the design parameters in a coarse manner, and then, coarsely optimized parameters are finely optimized using the genetic algorithm. Therefore the proposed method could solve global numerical optimization problems with continuous variables. The proposed two-step hybrid optimization algorithm could effectively optimize the grating structures for the purpose of polarization filter applications, and the optimized grating structures could selectively filter the incident light up to 99.8% as to TE or TM waves.