Multi‐Level Relaxation of NO in Collisions with Various Species

Glänzer, K.; Troe, J.

doi:10.1002/bbpc.19770810239

Ber Bunsenges Phys Chem

1977

DOI: 10.1002/bbpc.19770810239

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Multi‐Level Relaxation of NO in Collisions with Various Species

K. Glänzer

J. Troe

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Cited by 4 publications

References 8 publications

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Reactions of Vibrationally Excited Molecules

Wolfrum¹

1977

Ber Bunsenges Phys Chem

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A brief review is presented on reactions of vibrationally excited molecules in the gas phase. Recent experiments using laser optical pumping for a selective vibrational excitation and infrared and visible fluorescence, resonance absorption in the vacuum UV, nozzle beam and conventional mass spectrometry for detection of reactants and products are discussed and compared with theoretical predictions.

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Reactions of Vibrationally Excited Molecules

Wolfrum¹

1977

Ber Bunsenges Phys Chem

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Non-equilibrium thermal dissociation of diatomic molecules. I. Extraction of collision-induced rate constants from experimentally measured reaction rates as a function of temperature for ten diatomic molecules dilute in Ar

Teitelbaum

1988

Chemical Physics

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Measurement of absolute state-to-state rate constants for collision-induced transitions between spin-orbit and rotational states of NO(X 2Π, v = 2)

Sudbo

1982

The Journal of Chemical Physics

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Using a pulsed, time resolved IR–UV double resonance technique, we have measured initial and final state specific rates for collision-induced rotational and spin-orbit transitions in NO in its (X 2Π, v = 2) vibronic state. A systematic study of the rates was done for initial and final rotational states with J between 1/2 and 35/2, for both Ω = 1/2 and the Ω = 3/2 spin-orbit components of the X 2Π state. Collision partners were room temperature NO, He, Ar, N2, CO, and SF6. No propensity rules favoring ΔΩ = 0 or ΔJ = 0,±1 were observed, except in NO–He collisions, where ΔΩ = 0 was favored. The state-to-state rates do not vary much with initial state and fall off slowly with increasing ΔJ. Total cross sections for collision-induced rotational transitions were found to be tens of Å2, insensitive to initial state, and correlated with the size of the collision partner.

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Multi‐Level Relaxation of NO in Collisions with Various Species

Cited by 4 publications

References 8 publications

Reactions of Vibrationally Excited Molecules

Reactions of Vibrationally Excited Molecules

Non-equilibrium thermal dissociation of diatomic molecules. I. Extraction of collision-induced rate constants from experimentally measured reaction rates as a function of temperature for ten diatomic molecules dilute in Ar

Measurement of absolute state-to-state rate constants for collision-induced transitions between spin-orbit and rotational states of NO(X 2Π, v = 2)

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