This study concerns with robust tracking control problem for the longitudinal model of airbreathing hypersonic vehicles (AHVs). The AHVs include serious non-linearities, strong couplings, parametric perturbations and mismatched disturbances, which results in great difficultly in the controller design. By using back-stepping method and non-linear disturbance observer technique, a novel composite controller is proposed, which can guarantee system outputs asymptotically track their reference signals. A new idea is that disturbance estimations are introduced into virtual control law in each step to compensate the mismatched disturbances. As compared with other robust flight control methods for AHVs, the developed method exhibits not only excellent robustness and disturbance rejection performance but also the property of nominal performance recovery. Finally, the effectiveness of the proposed method is demonstrated by simulation results.