Three-dimensional textile fabrics are used as the reinforcing phase of the textile structural composites, and their geometry affect the physical and mechanical properties of composites. Based on the curvature and directions of the fiber tows in three-dimensional textile fabrics, four representative geometric units are proposed, namely, the orthogonal geometric unit, the curved geometric unit, the skew geometric unit, and the uniform distribution unit, respectively. Other units are the combinations or derivations of these representative geometric units. The relationship and performance characteristics of these representative geometric units are discussed in section “The relationship of RGUs.” The structural features of three-dimensional textile fabrics are illustrated on the mesoscopic scale, and the models are established to predict the geometric properties. The concepts of fabrics with stable structure, flexible structure, elastoplastic structure, and uniform structure are proposed. The fiber volume fractions and elastic characteristics of different structural fabrics are discussed. The classification of three-dimensional textile fabrics is conducive to investigate the relationship between geometry and property, forming a technical system and providing a theoretical basis for the selection of three-dimensional structural textile composites with different performance.