Multi-spectral investigation of ozone: Part I. Setup &amp; uncertainty budget

Janssen, Christof; Boursier, C.; Elandaloussi, Hadj; Jeseck, Pascal; Koshelev, Dmitry; Marie-Jeanne, Patrick; Rouillé, C.; Jacquemart, D.; Thibout, Florence; Vaudescal-Escudier, Mélanie; Té, Yao

doi:10.1016/j.jqsrt.2021.108051

Cited by 7 publications

(14 citation statements)

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“…For the ν 3 band, the goal has been achieved through a joint study of three experimental groups [ 19 , 20 , 21 , 22 , 23 ] and theory, using the DMS of [ 133 ].…”

Section: Recent Resultsmentioning

confidence: 99%

“…The first experiment was obtained using a new experimental setup in the LERMA laboratory [ 19 ]; using a Bruker IFS 125 permitted almost simultaneous recordings at 10 μm ( L = 5 cm) and 5 μm ( L = 20 cm). The ozone pressure was continuously monitored by UV absorption at 253.65 nm.…”

Section: Recent Resultsmentioning

confidence: 99%

“…Despite the fact that this value is significantly smaller than the natural width (see below), it limits the influence of the apparatus function (instrumental line shape (ILS)). New spectra were recorded with these Bruker instruments in Deutsch Forschungsanstalt Luft & Raumfahrt (DLR), Oberpfaffenhofen Germany, by Birk et al [ 173 ] and Laboratoire d’Etudes du Rayonnement et de la Matière en Astrophysique et Atmosphère (LERMA), Paris France, by Janssen et al [ 19 ] in the range of 10 microns, which lead to a precision of a sub percent for intensities, in agreement with ab initio calculations [ 17 , 18 , 24 ] (see Section 5.1 . Recent Results).…”

Section: Spectroscopy In the Infraredmentioning

confidence: 99%

“…The next step is a convolution using the apparatus function of the spectrometer. Details are given in [ 19 , 170 , 171 ]. Let us just remind that the FT apparatus function is itself a convolution of the sinc function, due to the limited path difference, and the iris function (ILS) of the spectrometer.…”

Section: Spectroscopy In the Infraredmentioning

confidence: 99%

“…The main part of this article, as indicated in the abstract, is devoted to high resolution infrared spectroscopy, which has a direct use in atmospheric applications. Three of these direct applications are particularly highlighted: the problem of agreement with an accuracy of 1% between spectroscopic data using suitable line lists in the infrared range has been solved [17][18][19][20][21][22][23][24]; the proof of the absence of a submerged barrier in the transition state range of the potential energy surface, having an impact on the modeling of isotopic exchange reactions in the O + OO collisions [25][26][27][28][29][30][31], which in turn could contribute to the anomalous isotope effect in ozone formation [11][12][13][14][15][16]; and a possible impact of the interactions among potential wells [32] on high energy ro-vibration levels [33].…”

Section: Introductionmentioning

confidence: 99%

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High Resolution Infrared Spectroscopy in Support of Ozone Atmospheric Monitoring and Validation of the Potential Energy Function

et al. 2022

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The first part of this review is a brief reminder of general information concerning atmospheric ozone, particularly related to its formation, destruction, observations of its decrease in the stratosphere, and its increase in the troposphere as a result of anthropogenic actions and solutions. A few words are said about the abandonment of the Airbus project Alliance, which was expected to be the substitute of the supersonic Concorde. This project is over due to the theoretical evaluation of the impact of a fleet in the stratosphere and has been replaced by the A380, which is now operating. The largest part is devoted to calculations and observations of the transitions in the infrared range and their applications for the atmosphere based both on effective models (Hamiltonian, symmetry rules, and dipole moments) and ab initio calculations. The complementarities of the two approaches are clearly demonstrated, particularly for the creation of an exhaustive line list consisting of more than 300,000 lines reaching experimental accuracies (from 0.00004 to 0.001 cm−1) for positions and a sub percent for the intensities in the 10 microns region. This contributes to definitively resolving the issue of the observed discrepancies between line intensity data in different spectral regions: between the infrared and ultraviolet ranges, on the one hand, and between 10 and 5 microns on the other hand. The following section is devoted to the application of recent work to improve the knowledge about the behavior of potential function at high energies. A controversial issue related to the shape of the potential function in the transition state range near the dissociation is discussed.

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“…For the ν 3 band, the goal has been achieved through a joint study of three experimental groups [ 19 , 20 , 21 , 22 , 23 ] and theory, using the DMS of [ 133 ].…”

Section: Recent Resultsmentioning

confidence: 99%

Section: Recent Resultsmentioning

confidence: 99%