Multi-Step Recycling of BF Slag Heat via Biomass for CO2 Mitigation

Conventional (anthracite, calcined petroleum coke, and coke) and non-conventional (biochar, and biocokes (3 wt.% torrefied wood, and 3 wt.% petroleum coke + 3 wt.% charcoal)) carbon-bearing sources have been studied for their use in electric arc furnace (EAF)-based steel production. Commonly, for the use of carbon sources in EAFs, one of the important properties is the content of fixed carbon, the release of volatiles as well as the elemental composition of inorganics. The properties of six carbon sources were analyzed by determining the proximate analysis, X-ray fluorescence analysis (XRF), coke reactivity index (CRI), and strength after reaction with CO2 (CSR), Brunauer–Emmett–Teller (BET) specific surface area and Barrett–Joyner–Halenda (BJH) pore size and volume analysis, ash chemical analysis, optical and scanning microscopy, Raman spectroscopy and X-ray diffraction (XRD) analysis. The results indicate biocoke as a promising option to replace conventional carbon-bearing sources. In the sample set, the fixed carbon, volatiles, and ash content of the biocokes were similar despite the total difference in additives. Additionally, the use of additives did not significantly affect the biocoke reactivity indices, but slightly decreased the strength after the reaction with CO2. Carbon-bearing sources have been characterized in terms of their structural properties. XRD analysis revealed that the amount of disordered carbon increased in the order: coke < calcined petroleum coke ~ biocoke (3 wt.% torrefied wood) < biocoke (3 wt.% petroleum coke + 3 wt.% charcoal) < biochar. The results obtained on the physical, chemical, and structural properties of carbon sources are the basis for further research on the behavior of slag foaming.

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Utilization of Renewable Carbon in Electric Arc Furnace-Based Steel Production: Comparative Evaluation of Properties of Conventional and Non-Conventional Carbon-Bearing Sources

Kieush

Schenk

Koveria

et al. 2023

Metals

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Analysis of Technological Pathways and Development Suggestions for Blast Furnace Low-Carbon Ironmaking

Li,

Zhao,

Guo

et al. 2024

Metals

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Under the global dual-carbon background, heightened public awareness of climate change and strengthened carbon taxation policies are increasing pressure on the steel industry to transition. Given the urgent need for carbon reduction, the exploration of low-carbon pathways in a blast furnace (BF) metallurgy emerges as crucial. Evaluating both asset retention and technological maturity, the development of low-carbon technologies for BFs represents the most direct and effective technical approach. This article introduces global advancements in low-carbon metallurgical technologies for BFs, showcasing international progress encompassing hydrogen enrichment, oxygen enrichment, carbon cycling technologies, biomass utilization, and carbon capture, utilization, and storage (CCUS) technologies. Hydrogen enrichment is identified as the primary technological upgrade currently, although its carbon emission reduction potential is limited to 10% to 30%, insufficient to fundamentally address high carbon emissions from BFs. Therefore, this article innovatively proposes a comprehensive low-carbon metallurgical process concept with the substitution of carbon-neutral biomass fuels at the source stage—intensification of hydrogen enrichment in the process stage—fixation of CCUS at the end stage (SS-IP-FE). This process integrates the cleanliness of biomass, the high-efficiency of hydrogen enrichment, and the thoroughness of carbon fixation through CCUS, synergistically enhancing overall effectiveness. This integrated strategy holds promise for achieving a 50% reduction in carbon emissions from BFs in the long processes. Critical elements of these core technologies are analyzed, assessing their cost-effectiveness and emission reduction potential, underscoring comprehensive low-carbon metallurgy as a pivotal direction for future steel industry development with high technological feasibility and emission reduction efficacy. The article also proposes a series of targeted recommendations, suggesting short-term focus on technological optimization, the medium-term enhancement of technology research and application, and the long-term establishment of a comprehensive low-carbon metallurgical system.

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Multi-Step Recycling of BF Slag Heat via Biomass for CO2 Mitigation

Cited by 2 publications

References 15 publications

Utilization of Renewable Carbon in Electric Arc Furnace-Based Steel Production: Comparative Evaluation of Properties of Conventional and Non-Conventional Carbon-Bearing Sources

Utilization of Renewable Carbon in Electric Arc Furnace-Based Steel Production: Comparative Evaluation of Properties of Conventional and Non-Conventional Carbon-Bearing Sources

Analysis of Technological Pathways and Development Suggestions for Blast Furnace Low-Carbon Ironmaking

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