The
concept and principles of chromatic engineering of electrolytes
have demonstrated charming prospects for constructing pluralistic
electrochromic devices. Here, we develop a synthetic design bearing
thermochromic and electrochromic behaviors based on the ionic liquid
(IL) microemulsion-based gel, driven by the intrinsic thermodynamic
stability of microemulsion and ionic conductivity of IL. The prepared
gel can tune light-scattering behaviors as the droplet expanded or
aggregated when the temperature is out of its thermodynamically stable
temperature range. Not only that, oil-phase IL ([EMIM]TFSI) as well
as introduced LiCl and LiTFSI endows it with satisfactory ionic conductivity,
making it able to be utilized as a free-standing electrolyte layer
for the electrochromic smart window. Therefore, the fabricated smart
window based on this gel and WO3 electrochromic layer successfully
realizes dual-stimuli responsiveness for both temperature and electric
field, possessing energy-saving combined with privacy protection function.
In addition, the component compatibility of microemulsion allows the
harmonious introduction of hydrophilic antifreeze moisturizer ethylene
glycol (EG) and hydrophobic ultraviolet absorber 2-hydroxy-4-(octyloxy)benzophenone
(2H4MBP), which further promotes the multifunctional integration of
a smart window for the strengthened safety factor, anti-freezing,
anti-drying, and anti-UV capabilities. Finally, we extend the application
of the IL microemulsion-based gel to an ionic writing plate based
on the same electrochromic mechanism. In brief, this innovative preparation
method paves the way for multifunctional electrochromic devices.