Rapid and accurate identification of precipitation clouds from satellite observations is essential for the research of quantitative precipitation estimation and precipitation nowcasting. In this study, we proposed a novel Convolutional Neural Network (CNN)-based algorithm for precipitation cloud identification (PCINet) in the daytime, nighttime, and nychthemeron. High spatiotemporal and multi-spectral information from the Fengyun-4A (FY-4A) satellite is utilized as the inputs, and a multi-scale structure and skip connection constraint strategy are presented in the framework of the algorithm to improve the precipitation cloud identification. Moreover, the effectiveness of visible/near-infrared spectral information in improving daytime precipitation cloud identification is explored. To evaluate this algorithm, we compare it with five other deep learning models used for image segmentation and perform qualitative and quantitative analyses of long-time series using data from 2021. In addition, two heavy precipitation events are selected to analyze the spatial distribution of precipitation cloud identification. Statistics and visualization of the experiment results show that the proposed model outperforms the baseline models in this task, and adding visible/near-infrared spectral information in the daytime can effectively improve model performance. More importantly, the proposed model can provide accurate and near-real-time results, which has important application in observing precipitation clouds.