The mechanism of thermal driving for launching accretion disk winds is interconnected with classical thermal instability (TI). Indeed, the effective scale height of irradiated accretion disk atmospheres is determined by the extent of the cold branch of the S-curve demarcating thermally unstable zones. In a recent paper, we demonstrated that as a result of this interconnectedness, radial wind solutions of X-ray heated flows are prone to becoming clumpy. In over two decades of numerical work, however, only smooth thermally driven disk wind solutions that approach a steady state have been found. In this paper, we show that the Bernoulli function determines whether or not the entropy mode can grow due to TI in dynamical flows. Based on this finding, we identify a critical radius, R u , beyond which TI should accompany thermal driving, resulting in clumpy disk wind solutions. Our numerical simulations reveal that clumpiness is a consequence of buoyancy disrupting the stratified structure of smooth solutions. Namely, instead of a thin transition layer separating the highly ionized disk wind from the cold phase atmosphere below, TI seeds the formation of hot spots below the transition layer that rise up, fragmenting the atmosphere. We find that these hot spots first appear within large scale vortices that form within R u . This results in the continual production of characteristic cold phase structures that we refer to as irradiated atmospheric fragments (IAFs). These IAFs resemble tsunamis upon interacting with the disk wind, as crests develop as they are advected outwards. The multiphase character of these solutions results from the subsequent disintegration of the IAFs, which takes place within a turbulent wake that reaches high enough elevations in the wind so as to be observable from sightlines as high as 45• . We discuss the properties of the absorption measure distribution (AMD) in detail, showing that dips in the AMD are not expected within TI zones. We also compute synthetic X-ray absorption lines to show that this complicated dynamics should result in spectral signatures such as a less sudden desaturation of Oviii Lyα and multiple absorption troughs in Fe xxv Kα.