Multichromophoric photoswitches for solar energy storage: from azobenzene to norbornadiene, and MOST things in between

Salthouse, Rebecca J.; Moth-Poulsen, Kasper

doi:10.1039/d3ta05972c

Cited by 24 publications

(4 citation statements)

References 110 publications

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“…The incorporation of “push–pull” substituents (combining acceptor and donor substituents to enhance homoconjugation) is an effective technique to increase the conjugation of the system. 37 However, it is important to note that while this approach enhances absorption and the solar match, it is clearly detrimental to the energy density as it increases the molecular weight. 24,38 Recent studies reported by Libuda and co-workers presented photoelectrochemical infrared reflection absorption spectroscopy (PEC-IRRAS), facilitating the real-time tracking of the full energy storage and release cycle via in situ vibrational spectroscopy.…”

Section: Charging Step: the Photoisomerization Reactionmentioning

confidence: 99%

State-of-the-art and challenges towards a Molecular Solar Thermal (MOST) energy storage device

Giménez-Gómez,

Magson,

Merino-Robledillo

et al. 2024

React. Chem. Eng.

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Section: Charging Step: the Photoisomerization Reactionmentioning

confidence: 99%

State-of-the-art and challenges towards a Molecular Solar Thermal (MOST) energy storage device

Giménez-Gómez,

Magson,

Merino-Robledillo

et al. 2024

React. Chem. Eng.

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“…142–144 Recently, advances in AZ-containing polymers for solar energy storage and release have been reviewed. 145–148 Here, we focus on several typical examples, as shown in Fig. 17.…”

Section: Potential Applicationsmentioning

confidence: 99%

Manipulation of photoresponsive liquid-crystalline polymers and their applications: from nanoscale to macroscale

Ji,

2024

J. Mater. Chem. C

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“…Indeed, photochemistry can play a role in novel methods that can convert or even store energy in molecules. 255 Here it is important to note that in order to store energy it is necessary to drive endothermic reactions by light (Figure 5). Only then will part of the solar energy be stored (ΔH > 0) in the newly formed molecular bonds.…”

Section: Microfluidic Photocatalysismentioning

confidence: 99%

Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop

Beil,

Bonnet,

Casadevall

et al. 2024

JACS Au

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Photocatalysis is a versatile and rapidly developing field with applications spanning artificial photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular structures, utilization of abundant metals and organocatalysts, sustainable synthesis, and plastic degradation. In this Perspective, we summarize conclusions from an interdisciplinary workshop of young principal investigators held at the Lorentz Center in Leiden in March 2023. We explore how diverse fields within photocatalysis can benefit from one another. We delve into the intricate interplay between these subdisciplines, by highlighting the unique challenges and opportunities presented by each field and how a multidisciplinary approach can drive innovation and lead to sustainable solutions for the future. Advanced collaboration and knowledge exchange across these domains can further enhance the potential of photocatalysis. Artificial photosynthesis has become a promising technology for solar fuel generation, for instance, via water splitting or CO2 reduction, while photocatalysis has revolutionized the way we think about assembling molecular building blocks. Merging such powerful disciplines may give rise to efficient and sustainable protocols across different technologies. While photocatalysis has matured and can be applied in industrial processes, a deeper understanding of complex mechanisms is of great importance to improve reaction quantum yields and to sustain continuous development. Photocatalysis is in the perfect position to play an important role in the synthesis, deconstruction, and reuse of molecules and materials impacting a sustainable future. To exploit the full potential of photocatalysis, a fundamental understanding of underlying processes within different subfields is necessary to close the cycle of use and reuse most efficiently. Following the initial interactions at the Lorentz Center Workshop in 2023, we aim to stimulate discussions and interdisciplinary approaches to tackle these challenges in diverse future teams.

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Multichromophoric photoswitches for solar energy storage: from azobenzene to norbornadiene, and MOST things in between

Abstract: The ever-increasing global demands for energy supply and storage have led to numerous research efforts into finding and developing renewable energy technologies. Molecular solar thermal energy storage (MOST) systems utilise...

Cited by 24 publications

References 110 publications

State-of-the-art and challenges towards a Molecular Solar Thermal (MOST) energy storage device

State-of-the-art and challenges towards a Molecular Solar Thermal (MOST) energy storage device

Manipulation of photoresponsive liquid-crystalline polymers and their applications: from nanoscale to macroscale

Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop

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