Multielectron‐Transfer‐based Rechargeable Energy Storage of Two‐Dimensional Coordination Frameworks with Non‐Innocent Ligands

Wada, Keisuke; Sakaushi, Ken; Sasaki, Sono; Nishihara, Hiroshi

doi:10.1002/ange.201802521

Cited by 51 publications

(36 citation statements)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The X-ray crystal structure analysis of 5 revealed that the coordination bonds established a 2D network with a cavity ~12 Å in size. Compared with the previously reported MOFs used as the active materials [ 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 ] and Stokes radii of the Li ion (~4.8 Å in propylene carbonate) [ 58 ], the cavity in the 2D coordination sheet of 5 is large enough to be used as a space for storage and transfer of Li ions. On the other hand, in the π-stacking structure, the sheets stacked non-parallelly, and the coordinating sites in the next sheet partially cover the cavity ( Figure 8 a) and, thus, the 1D channel narrowed to ~6 Å ( Figure 5 b).…”

Section: Discussionmentioning

confidence: 99%

“…Furthermore, a cavity in the coordination network can be utilized as a space for Li-ion to increase the efficiency and speed of giving and receiving of electrons in charge–discharge processes. From these viewpoints, redox-active MOFs were widely investigated as cathode and anode active materials of LIB [ 27 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 , 37 , 38 ].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

2D Coordination Network of Trioxotriangulene with Multiple Redox Abilities and Its Rechargeable Battery Performance

Murata

Koide

Nobukuni

et al. 2020

IJMS

View full text Add to dashboard Cite

A three-fold symmetric trioxotriangulene derivative with three pyridyl groups as coordinating sites was designed and synthesized. In a cyclic voltammetry measurement, the trioxotriangulene skeleton exhibited a multi-stage redox ability from neutral radical to radical tetra-anion species. In the zinc complex of monoanion species, three pyridyl groups coordinated to the zinc ion to build up a two-dimensional coordination network with a cavity larger than 12 Å in diameter. This complex was utilized as a cathode active material of a lithium ion battery, and it exhibited a capacity of ca. 60 mAh g−1 per the weight of the active material with a stable cycling performance up to 1000 cycles. This work shows that the coordination network formed by the trioxotriangulene-based ligand was effective in the improvement of cycle performance of the organic rechargeable battery.

show abstract

Section: Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

2D Coordination Network of Trioxotriangulene with Multiple Redox Abilities and Its Rechargeable Battery Performance

Murata

Koide

Nobukuni

et al. 2020

IJMS

View full text Add to dashboard Cite

show abstract

“…The uneven distribution, gradual consumption, rarity, and increasing price of Li resources themselves to some great extent limit the large‐scale application of LIBs in the near future. Investigations for alternative rechargeable batteries based on earth‐abundant elements have become even more significant 80 . Na‐ion batteries (SIBs) are attractive and promising substitute for LIBs because of the abundant sodium species and their high energy storage properties that can compete with LIBs 81 .…”

Section: Conductive Mofs Towards Electrochemical Energy‐related Applimentioning

confidence: 99%

Conductive metal‐organic frameworks: Recent advances in electrochemical energy‐related applications and perspectives

et al. 2020

View full text Add to dashboard Cite

Metal‐organic frameworks (MOFs), typically constructed with metallic nodes and organic linkers, have influenced the development of modular solid materials. Their adjustable molecular structure provides a remarkable variety of MOF‐based solid‐state structures towards diverse applications. However, the low conductivity of traditional MOFs extremely hinders their applications in electronic and electrochemical devices. The emerging conductive MOFs, generally possessing two‐dimensional layered structures, are endowed with both the structural merits of common MOFs and exceptional electronic/ionic conductivities. Besides, the selection and optimization of ligands and metal centers, as well as synthetic methods enormously affects the intrinsic conductivity of conductive MOFs. The distinctive crystal structures and superb conductivity promise their appealing applications in electrochemical energy‐related fields. In the review, we mainly summarize representative crystal features, conducting mechanisms and recent advances in rational design and synthesis of conductive MOFs, along with their versatile applications as electrodes for electrochemical capacitors and rechargeable batteries, and as catalysts towards electrocatalysis. Finally, the involved challenges and future trends/prospects of the conductive MOFs for electrochemical energy‐related applications are further proposed.

show abstract

“…This mechanism is widely accepted in recent literatures. [17] Some reports [14,42,58] also suggested that Ni(opda) 2 can lose two electrons,l eading to [Ni II (opda) 2 ] 2+ (Supporting Information, Figure S23). This claim makes it plausible that Ni-BTAc an even undergo four-electron redox reactions during cycling.…”

Section: Forschungsartikelmentioning

confidence: 99%

A one-dimensional π-d conjugated coordination polymer for sodium storage with catalytic activity in Negishi coupling

Yuan

Chen

2019

International Photonics and OptoElectronics Meeting 2019 (OFDA, OEDI, ISST, PE, LST, TSA)

View full text Add to dashboard Cite

p-d Conjugated coordination polymers (CCPs) have attracted muchattention for various applications,although the chemical states and structures of many CCPs are still blurry. Now,aone-dimensional (1D) p-d conjugated coordination polymer for high performance sodium-ion batteries is presented. The chemical states of the obtained coordination polymer are clearly revealed. The electrochemical process undergoes at hree-electron reaction and the structure transforms from C=Nd ouble bonds and Ni II to CÀNs ingle bonds and Ni I ,r espectively.Our unintentional experiments provided visual confirmation of Ni I .T he existence of Ni I was further corroborated by its X-raya bsorption near-edge structure (XANES) and its catalytic activity in Negishi cross-coupling.Supportinginformation and the ORCID identification number(s) for the author(s) of this article can be found under: https://doi.

show abstract

Multielectron‐Transfer‐based Rechargeable Energy Storage of Two‐Dimensional Coordination Frameworks with Non‐Innocent Ligands

Cited by 51 publications

References 37 publications

2D Coordination Network of Trioxotriangulene with Multiple Redox Abilities and Its Rechargeable Battery Performance

2D Coordination Network of Trioxotriangulene with Multiple Redox Abilities and Its Rechargeable Battery Performance

Conductive metal‐organic frameworks: Recent advances in electrochemical energy‐related applications and perspectives

A one-dimensional π-d conjugated coordination polymer for sodium storage with catalytic activity in Negishi coupling

Contact Info

Product

Resources

About