Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity

Li, Ang; Wang, Yanhong; Tian, Haotian; Yalikun, Alimujiang; Journaux, Yves; Luo, Min; Lu, Hongcheng

doi:10.1016/j.cclet.2023.108780

Cited by 5 publications

(3 citation statements)

References 50 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These NCS materials not only exhibit SHG but also possess a spectrum of physical attributes, including pyroelectricity, circular dichroism, enantiomorphism, and SHG, contingent upon their crystal classes . When a material with an NCS structure is synthesized using specific materials, it has the potential to exhibit not only physical properties but also unique multifunctional characteristics. , However, the rarity of NCS structures in nature, constituting merely 19% of inorganic crystals, has prompted innovative methods for their synthesis. Approaches utilizing second-order Jahn–Teller distortive cations (Ti 4+ , V 5+ , Mo 6+ , etc.…”

Section: Introductionmentioning

confidence: 99%

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

Koh,

2024

Crystal Growth & Design

View full text Add to dashboard Cite

Two novel Cd-based noncentrosymmetric (NCS) chiral coordination polymers (CPs), [Cd 2 ((S,S)-IBPhe) 2 )] (IBPhe = isophthaloyl-bis-phenylalanine), have been synthesized through hydrothermal reactions. Cd(S) and Cd(R) crystallize in the monoclinic polar space group, P2 1 (No. 4), and exhibit rigid one-dimensional (1D) chain structures maintained by π−π interactions between organic ligands, as well as C−H•••π interactions with adjacent chains. The solid-state photoluminescence data reveal intriguing blue light emission characterized by a phosphorescence decay time of about 0.41 ms, attributed to ligand-to-ligand charge transfer effects. Impressively, these Cd-based compounds exhibit a high degree of stability across various solvents and pH conditions. Furthermore, their exceptional adsorption capacities for Congo red are evidenced by maximum adsorption efficiencies of 850.82 mg/g for Cd(S) and 817.71 mg/g for Cd(R). These findings underline the potential of these NCS chiral coordination polymers for diverse applications ranging from efficient dye removal to enhanced photoluminescence.

show abstract

Section: Introductionmentioning

confidence: 99%

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

Koh,

2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

“…Low-dimensional quantum magnets are of great interest due to their exotic quantum phenomena such as spin-liquid state, relation to high-temperature superconductivity, and potential application in quantum computing. − One-dimensional (1D) chain magnetic systems were first studied because they are the most fundamental and simplest low-dimensional quantum magnets. Particularly, Haldane conjectured that spin chains with half-integer and integer spins exhibit different magnetic behaviors.…”

Section: Introductionmentioning

confidence: 99%

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Yalikun,

Wang,

et al. 2024

Inorg. Chem.

Self Cite

View full text Add to dashboard Cite

A series of analogous chain selenite chlorides Ba 2 M(SeO 3 ) 2 Cl 2 (M = Cu 1, Ni 2, Co 3, Mn 4) and Pb 2 Cu(SeO 3 ) 2 Cl 2 5 with tunable spin S from S = 1/2 to S = 5/2 have been hydrothermally synthesized and characterized. These analogues crystallized in the orthorhombic Pnnm space group (monoclinic P2 1 /n space group for 5) all containing M 2+ −SeO 3 −M 2+ spin chains, which are further separated by the Ba 2+ ions (Pb 2+ for 5). The magnetic susceptibility results of 1, 2, and 5 show broad maxima around 80.0, 18.9, and 78.0 K, respectively, indicating good one-dimensional (1D) magnetism. Meanwhile, no long-range order (LRO) is observed down to 2 K for both 1 and 5, while the isostructural compounds 2, 3, and 4 exhibit LRO at 3.4 K, 10.8 K, and 5.7 K, respectively, which are further confirmed by the heat capacity and electron spin resonance results, as well as the observed spin-flop transitions in the M−H curves measured at 2 K below T N . The magnetizations of 1−5 at 7 T are still far from saturation. In addition, thermal stability and FT-IR and UV−vis−NIR spectroscopy of 1−5 are reported.

show abstract

“…Low-dimensional frustrated magnetic systems have attracted great interest in the past decades due to their exotic quantum phenomena such as quantum spin liquid and their potential applications in spintronics and quantum computing. [1][2][3][4][5][6][7] The common spin frustrated systems, including one-dimensional (1D) systems of zigzag chains, [8][9][10] diamond chains, 11 and spin ladders; 12 2D systems of triangular lattices (Fig. 1a), 13 Kagomé lattices (Fig.…”

Section: Introductionmentioning

confidence: 99%

KMB₄O₆F₃ (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO₃ units

Wang,

Li,

Dou

et al. 2023

Dalton Trans.

Self Cite

View full text Add to dashboard Cite

show abstract

Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity

Cited by 5 publications

References 50 publications

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

KMB₄O₆F₃ (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO₃ units

Contact Info

Product

Resources

About

Multifunctional properties of a polar spin chain compound [N(C3H7)4][Cu(C8H4NO4)]·H2O exhibiting both one-dimensional magnetism and nonlinear optical activity

Cited by 5 publications

References 50 publications

[Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

[Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

Analogous Chain Selenite Chlorides Ba2M(SeO3)2Cl2 (M = Cu2+, Ni2+, Co2+, Mn2+) and Pb2Cu(SeO3)2Cl2 with Tunable Spin S: Syntheses and Characterizations

KMB4O6F3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO3 units

Contact Info

Product

Resources

About

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

[Cd₂((S,S)-IBPhe)₂(2,2′-bipy)₂]·2H₂O and [Cd₂((R,R)-IBPhe)₂(2,2′-bipy)₂]·2H₂O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

KMB₄O₆F₃ (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO₃ units