In the photovoltaic (PV) field, the outdoor evaluation of a PV system is quite complex, due to the variations of temperature and irradiance. In fact, the diagnosis of the PV modules is extremely required in order to maintain the optimum performance. In this paper, an artificial neural network (ANN) is proposed to build and train the model, and evaluate the PV module performance by mean bias error, mean square error and the regression analysis. We take temperature, irradiance and a specific voltage for input, and a specific current value for output, repeat several times in order to obtain an I-V curve. The main feature lies to the data-driven black-box method, with the ignorance of any analytical equations and hence the conventional five parameters (serial resistance, shunt resistance, non-ideal factor, reverse saturation current, and photon current). The ANN is able to predict the I-V curves of the Si PV module at arbitrary irradiance and temperature. Finally, the proposed algorithm has proved to be valid in terms of comparison with the testing dataset.