The objective of this work is to advance the stateof-the-art in the characterization of the multipactor effect in dielectric materials. The materials studied are the most commonly used dielectrics in space applications, namely, Alumina, Rexolite, Rogers RT5870, Rohacell, Teflon and Ultem 1000. In this context, a new family of coaxial waveguide components, covering the Land S-bands, with a wideband, lowpass response has been designed, and six different prototypes have been specifically optimized and manufactured. The six prototypes have then been used to simulate and measure the multipactor breakdown susceptibility charts for the six dielectric materials investigated. Finally, the simulation results are compared with the results of the measurement campaign indicating good agreement.