A compact multi-gas sensor has been
developed for simultaneous
detection of atmospheric carbon monoxide (CO), nitrous oxide (N2O), and methane (CH4). Instead of the traditional
time-division multiplexing detection technique, two lasers having
center emission wavelengths of 1.653 μm (near-infrared (NIR)
diode feedback (DFB) laser diode) and 4.56 μm (mid-infrared
(MIR) quantum cascade laser) were simultaneously coupled to a multipass
cell using a dichroic mirror, which significantly decreased the complexity
of the measurement and increased the temporal resolution of the spectrometer.
Wavelength modulation spectroscopy (WMS) with the second-harmonic
detection technique (WMS-2f) was used to improve the detection sensitivity.
A LabVIEW-based digital lock-in amplifier (DLIA) algorithm and system
control unit was developed to make the system more compact and flexible.
Allan deviation analysis indicates that detection limits of 6.36 ppb
by volume for CO, 4.9 ppb by volume for N2O, and 23.6 ppb
by volume for CH4 are obtained at 1 s averaging time, and
the sensitivity can be improved to 0.44 ppb for CO, 0.41 ppb for N2O, and 2 ppb for CH4 at an optimal averaging time
of 900 s. Two-day real-time measurement in ambient air was performed
to demonstrate the long-term stability of the sensor system.