Fine structure in the α decay of high-spin isomers in 155 Lu(25/2 −) and 156 Hf (8 +) has been studied for the first time using αγ-coincidence analysis. Three new α decays from 155 Lu(25/2 −) and two from 156 Hf (8 +) have been identified, populating seniority s > 1 states in the N = 82 nuclei 151 Tm and 152 Yb, respectively. The reduced hindrance factors of the α decays support the previous configuration assignments of the populated states. This is the first observation of states with excitation energy greater than 1.5 MeV being populated following α decay in nuclei outside of the 208 Pb region.