2022
DOI: 10.1016/j.molliq.2022.118824
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Multiple ion (Al3+, Cr3+, Fe3+, and Cu2+) sensing using a cell-compatible rhodamine-phenolphthalein-derived Schiff-base probe

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Cited by 45 publications
(11 citation statements)
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“…The ESIPT photoreaction is extremely sensitive to the media surrounding the molecules of ESIPT-fluorophores. The reaction is affected by such factors as the nature of solvents, [42][43][44][45] acidity and basicity of media, 46,47 protonation/ deprotonation, [48][49][50][51] the presence of metal ions, 52,53 packing in the solid state, 54,55 etc. The formation of hydrogen bonds between the proton-donating group of an ESIPT-fluorophore and neighbouring molecules can break the intramolecular hydrogen bond and result in the emission of the normal form only.…”
Section: Introductionmentioning
confidence: 99%
“…The ESIPT photoreaction is extremely sensitive to the media surrounding the molecules of ESIPT-fluorophores. The reaction is affected by such factors as the nature of solvents, [42][43][44][45] acidity and basicity of media, 46,47 protonation/ deprotonation, [48][49][50][51] the presence of metal ions, 52,53 packing in the solid state, 54,55 etc. The formation of hydrogen bonds between the proton-donating group of an ESIPT-fluorophore and neighbouring molecules can break the intramolecular hydrogen bond and result in the emission of the normal form only.…”
Section: Introductionmentioning
confidence: 99%
“…Erdemir et al reported a bisphenol A incorporated rhodamine dye (80) for the identification of Zn 2+ in acetonitrile and Hg 2+ in CH 3 CN-water (8/2, v/v, HEPES, pH 7.0). 94 Hg 2+ induced the opening of the spirolactam ring which resulted in high fluorescence at 580 nm. On the other hand, Zn 2+ could not open the ring of the compound and gave fluorescence at 468 nm.…”
Section: Differential Detection By Rhodamine Based Chemosensorsmentioning
confidence: 99%
“…A reaction between phenolphthaleindialdehyde and rhodamine B hydrazide afforded compound 78 (Scheme 13) which could detect multiple cations in CH 3 OH–water (9 : 1, v/v, HEPES buffer, pH 7.2). 94 It displayed a significant absorbance increase at 555 nm in the presence Cu 2+ and Fe 3+ and high fluorescence at ∼585 nm with Al 3+ and Cr 3+ although the last couple of cations showed pink coloration. All the cations induced ring opening and complexation via amide oxygen, azomethine nitrogen and phenolic oxygen atoms.…”
Section: Introductionmentioning
confidence: 95%
“…The ESIPT photoreaction in ESIPT-capable molecules depends strongly on the nature of media, [35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50] on substituents introduced in the core of an ESIPT-capable molecule and on the degree of p-conjugation between different moieties of the molecule. [51][52][53][54][55][56][57][58][59][60][61][62][63][64][65][66][67][68][69] These factors affect the electronic structure of the molecule and can induce barriers between the normal and tautomeric forms on the potential energy surfaces (PESs) in the excited state, causing partial or even full frustration of the proton transfer.…”
Section: Introductionmentioning
confidence: 99%