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SummaryThe application of multiple injections and correlation techniques in capillary zone electrophoresis, a method known for its high detection limits, is described. An experimental electrokinetic injection device, particulary suited for fast and reproducible multiple injections is used in combination with a conventional CZE system. The results show a considerable reduction of the detection limit, in agreement with the experience in the already fully developed correlation chromatographic methods, and in agreement with the theoretical predicted values.