Multivariate indium–organic frameworks for highly efficient carbon dioxide capture and electrocatalytic conversion

Abstract

It is crucial to design highly selective and cost-effective materials for the efficient CO2 uptake and the desirable transformation of CO2 into fuels or high-value chemical products. Here, we synthesize...

Visualization and analysis of the transformation and development of thermal power plants under the low‐carbon policy

“…What's more, enterprises are required to take responsibility for their actions in polluting the environment and to make corresponding acts of compensation for damage to the environment. Under this impetus, technological developments, process updates, and process developments are continuously realized 39 . While not giving up thermal power generation, new energy generation is being vigorously developed.…”

“…Under this impetus, technological developments, process updates, and process developments are continuously realized. 39 While not giving up thermal power generation, new energy generation is being vigorously developed. New hot issues are thus emerging.…”

Regulation Strategy of Nanostructured Engineering on Indium‐Based Materials for Electrocatalytic Conversion of CO2

“…The first classic structural model is the porous structure, which has significant advantages in providing more active sites for the adsorption of CO 2 and promoting the diffusion mass transfer of CO 2 to improve the catalytic kinetic process. [ 141–143 ] Given these promising application potentials, researchers have been working to develop In‐based materials with porous structures by devising different synthesis strategies, including the electrodeposition methods for the In nano foam material (DF In and CADF In), [ 144 ] 3D layered porous indium catalyst (hp‐In), [ 145 ] dendritic Cu‐In catalyst (Cu‐In‐30), [ 146 ] hydrothermal method for Indium‐based metal–organic framework (In‐BDC), [ 147 ] multivariate indium–organic frameworks (InCo‐ABDBC‐HIN), [ 148 ] as well as coprecipitation method for In‐Co PBA nanocube (In 2 O 3 @In‐Co PBA) [ 149 ] and mesoporous indium electrocatalyst (mp‐In). [ 150 ] These electrocatalysts with unique porous structures show significantly improved activity for CO 2 RR benefiting from the larger electrochemical active area, enhanced charge transfer ability and strong structural stability.…”

Robust Nitro-Functionalized {Zn3}-Organic Framework for Excellent Catalytic Performance on Cycloaddition Reaction of CO2 with Epoxides and Knoevenagel Condensation

“…Crystalline porous metal–organic frameworks (MOFs), as a kind of emerging new materials with structural diversity, designability, tailorability and ultrahigh-specific surface area, have gradually become a hot research topic in coordination chemistry and materials science community because of their various topological structures and physicochemical properties. − Up to now, a large number of developed MOFs were found to have promising applications such as catalysis, adsorption, and fluorescence recognition. − Catalysis has been one of the most rapidly developing application fields because of the high density and uniformly dispersed catalytic active sites in the confined space of MOFs, which can be regulated under the guidance of reticular chemistry. − Therefore, expected frameworks can be obtained by changing the type of metal nodes and/or ligands. So far, although the unique geometric characteristics of transition metal ions can promote the design of unique MOF networks, the design of highly coordinated porous solids is still a challenge because the enthalpy factor of transition metals is conducive to the formation of dense materials.…”