We report results from shell model studies of muon capture on 40 Ca to low-lying levels of 40 K. We discuss the comparison between calculated capture rates, measured capture rates and analogous transitions in (e,e ′ ) scattering in terms of the particle-hole structure of the 40 Ca-40 K nuclei. We highlight the 40 Ca(0 + , 0)→ 40 K(0 − , 2626) axial charge transition and its sensitivity to the induced pseudoscalar coupling g p of the proton's weak interaction. In addition, we address the hindrance of unique first-forbidden transitions due to particle-hole interactions and the emergence of allowed Gamow-Teller transitions due to ground state correlations. Lastly, we examine the longitudinal alignment of 40 K recoils following muon capture, and discuss this possibility for independently determining the induced coupling g p .