MXenes: Advances in the synthesis and application in supercapacitors and batteries

Wasnik, Kundan; Pawar, Meenakshi D.; Raphael, Leya Rose; Pullanchiyodan, Abhilash; Shelke, Manjusha V.; Raghavan, Praveen

doi:10.1557/s43578-022-00770-4

Cited by 8 publications

(5 citation statements)

References 155 publications

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“… 77 Ammonium hydrogen bifluoride (NH 4 HF 2 ) and ammonium fluoride are commonly employed in the synthesis of Ti 3 C 2 from Ti 3 AlC 2 . 78 An alternative technique involves combining Ti 4 AlN 3 powder with a specific mixture of molten fluoride salts, such as NaF, KF, and LiF. For half an hour, the mixture is blended at 550 °C.…”

Section: Mxene Materials Properties and Synthesismentioning

confidence: 99%

“… 81 Chemical vapour deposition (CVD) is a commonly employed method for MXene synthesis, providing several benefits over traditional top-down approaches. 78 Plasma enhancement is utilised in the traditional chemical vapour deposition process to improve material quality and enable synthesis at reduced temperatures. The synthesis methods for MXenes are continuously evolving due to the rapid expansion of the domain.…”

Section: Mxene Materials Properties and Synthesismentioning

confidence: 99%

“…The synthesis methods for MXenes are continuously evolving due to the rapid expansion of the domain. 78 MXene synthesis via a bottom-up approach is shown in Fig. 6 .…”

Section: Mxene Materials Properties and Synthesismentioning

confidence: 99%

See 2 more Smart Citations

Beyond graphene: exploring the potential of MXene anodes for enhanced lithium–sulfur battery performance

Sandhu,

Imtiaz,

Raza

et al. 2024

RSC Adv.

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Section: Mxene Materials Properties and Synthesismentioning

confidence: 99%

Section: Mxene Materials Properties and Synthesismentioning

confidence: 99%

See 1 more Smart Citation

Beyond graphene: exploring the potential of MXene anodes for enhanced lithium–sulfur battery performance

Sandhu,

Imtiaz,

Raza

et al. 2024

RSC Adv.

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“…Hence, the energy density can be increased either by increasing the specific capacitance of the electrode or by increasing the potential window of electrolytes. A large volume of research work was done on either aspect by making new electrode materials with ultrahigh specific capacitance like MXenes − and by using wide-voltage-window nonaqueous electrolytes. − …”

Section: Introductionmentioning

confidence: 99%

High-Potential Aqueous Asymmetric Supercapacitor Based on 2D Molybdenum Disulfide and Vanadium Pentoxide Electrodes

Pullanchiyodan,

Haridasan,

Sreeram

et al. 2024

Energy Fuels

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A wide-operating-voltage asymmetric supercapacitor (ASC) based on an aqueous electrolyte has great promise in the current energy storage technologies by providing better energy density, power density, safety, cost effectiveness, and long cycle life. Herein, the fabrication of an ASC using a 2D transition metal dichalcogenide (molybdenum disulfide (2D MoS 2 )) and a transition metal oxide (vanadium pentoxide, V 2 O 5 ) as the negative and positive electrode, respectively, was demonstrated. The electrochemical and galvanostatic charge−discharge analysis of both positive (V 2 O 5 ) and negative electrodes (2D MoS 2 ) was carried out in a threeelectrode setup. The results show stable operating potentials of −0.9 and 1.0 V for MoS 2 and V 2 O 5 electrodes, respectively. By combining these positive and negative electrodes in a 1 M sodium sulfate (Na 2 SO 4 ) aqueous electrolyte, the developed ASC reveals a wide operating potential (2.0 V). The electrochemical analysis of the ASC in a stable operating potential of 1.4 V gives an areal capacitance and energy density of 30 mF/cm 2 and 8.2 μWh/cm 2 , respectively, at a scan rate of 1 mV s −1 . The performance of the ASC was analyzed for 5000 continuous charge−discharge cycles at a higher current of 3.5 mA. After 5000 cycles, the ASC exhibits more than 80% capacitance retention with a specific capacitance of 0.85 mF/cm 2 .

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“…1(b)-(d)). 40 Carbonaceous materials, transition metal oxides (TMOs), two-dimensional (2D) materials, conducting polymers and nanocomposites are the most extensively used electrode materials in SCs. 27,29,41,42 Among these, the transition metal oxides have promising results in attaining high specific capacitance and better energy density.…”

Section: Introductionmentioning

confidence: 99%

Recent advances in electrospun fibers based on transition metal oxides for supercapacitor applications: a review

et al. 2023

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MXenes: Advances in the synthesis and application in supercapacitors and batteries

Cited by 8 publications

References 155 publications

Beyond graphene: exploring the potential of MXene anodes for enhanced lithium–sulfur battery performance

Beyond graphene: exploring the potential of MXene anodes for enhanced lithium–sulfur battery performance

High-Potential Aqueous Asymmetric Supercapacitor Based on 2D Molybdenum Disulfide and Vanadium Pentoxide Electrodes

Recent advances in electrospun fibers based on transition metal oxides for supercapacitor applications: a review

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