(N-Arylaminomethyl)pyridine-N-oxides: Synthesis and characterization of potential ligand systems and the formation of their N,O-chelate aluminum complexes
“…The hydroxylaminato oxygen atom coordinates towards the aluminium atom with a distance O(1)-Al(1) of 1.840(1) A ˚. This value can be compared to those of literature known compounds and typical examples are (aminomethyl-tert-butylphenolato)dimethylaluminium 12 (1.762 A ˚), (acetoneoximato)dimethylaluminium 13 (1.791 A ˚) or (diisopropylphenylamido-2-propyl)pyridine oxide)dimethylaluminium 14 (1.859 A ˚).…”
“…The hydroxylaminato oxygen atom coordinates towards the aluminium atom with a distance O(1)-Al(1) of 1.840(1) A ˚. This value can be compared to those of literature known compounds and typical examples are (aminomethyl-tert-butylphenolato)dimethylaluminium 12 (1.762 A ˚), (acetoneoximato)dimethylaluminium 13 (1.791 A ˚) or (diisopropylphenylamido-2-propyl)pyridine oxide)dimethylaluminium 14 (1.859 A ˚).…”
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