1997
DOI: 10.1016/s0022-328x(96)06444-3
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N-(N′, N′, N″, N″-tetramethyl) guanidine-substituted phosphines as monodentate, bidentate or tridentate ligands in transition metal chemistry

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Cited by 20 publications
(2 citation statements)
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“…The bonding mode in 6 can be compared with that found in some complexes of guanidino-substituted phosphanes, in which an amino group N atom and a P atom are coordinated to a metal. [21] We calculated the structure of complex 6 using the B3LYP functional in combination with the def2-TZVP basis set. A comparison between calculated and experimentally determined structures can be found in Table S1 of the Supporting Information.…”
Section: Resultsmentioning
confidence: 99%
“…The bonding mode in 6 can be compared with that found in some complexes of guanidino-substituted phosphanes, in which an amino group N atom and a P atom are coordinated to a metal. [21] We calculated the structure of complex 6 using the B3LYP functional in combination with the def2-TZVP basis set. A comparison between calculated and experimentally determined structures can be found in Table S1 of the Supporting Information.…”
Section: Resultsmentioning
confidence: 99%
“…Bailey et al have investigated the behaviour of monodentate guanidine ligands,7 whereas Coles and co‐workers introduced bicyclic guanidine systems into coordination chemistry 2. These systems are mostly not peralkylated, but meanwhile, peralkylated phosphorus‐8 or silicon‐bridged9 bis‐guanidine systems have been developed. Pruszynski10 Pohl11 and Sundermeyer12 and their co‐workers have investigated peralkylated guanidine systems with organic bridges.…”
Section: Introductionmentioning
confidence: 99%