Unintentional impurity incorporation in N‐polar GaN films grown by metalorganic vapor phase epitaxy (MOVPE) was investigated. The influences of growth conditions on the impurity concentration, electrical properties, and optical properties were discussed. Secondary‐ion mass spectroscopy showed that both concentrations of carbon and oxygen were changed by growth conditions. With decreasing H2/(H2 + N2) ratio, the carbon concentration increased, while the oxygen concentration decreased. At higher V/III ratios, the oxygen concentration decreased. Nitrogen‐rich carrier gas and a high V/III ratio can decrease oxygen incorporation in the N‐polar GaN epitaxial layer. The growth parameters discussed in this study are concluded to affect the adsorption/desorption properties of impurities. Based on these results, the electrical properties of N‐polar III‐nitrides can also be controlled by choosing the appropriate MOVPE growth conditions. This technology will lead to improvements in N‐polar III‐nitride‐based device performance.