N,S-heterocyclic carbene containing benzothiazol-2-ylidene-Ru(II) and Pd(II) new complexes functionalized with butyl linked carbazole moiety: Synthesis, characterization and their catalytic efficiency and electropolymerizations

Karakaş, Hayriye; Güzel, Merve; Ak, Metin; Kılınçarslan, Rafet; Özdemir, Namık

doi:10.1016/j.eurpolymj.2022.111630

European Polymer Journal

2022

DOI: 10.1016/j.eurpolymj.2022.111630

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N,S-heterocyclic carbene containing benzothiazol-2-ylidene-Ru(II) and Pd(II) new complexes functionalized with butyl linked carbazole moiety: Synthesis, characterization and their catalytic efficiency and electropolymerizations

Hayriye Karakaş

Merve Güzel

Metin Ak

et al.

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Cited by 7 publications

References 103 publications

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Synthesis and Characterization of Ru(II)−NSHC Catalysts Bearing Thiamine Analogs in Water‐Solvent Transfer Hydrogenation Catalysis

Kılınçarslan,

Menderes,

Tuncer

et al. 2024

Eur J Inorg Chem

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Thiamine analogues with 3‐methyl and 4‐(2‐hydroxyethyl) substituents on the backbone of thiazole ring, were used to synthesize monodentate Ru(II)‐thiazolylidene complexes in a single step via transmetalation under mild conditions. These novel complexes catalyze the conversion of ketones and aldehydes to alcohols by transfer hydrogenation in a 5:2 HCO2H/NEt3 buffer in water. However, their efficiency was found to be much lower than the thiamine‐derived bidentate Ru(II) complexes, which strongly indicates that the ‘N‐H’ plays a crucial role in the reaction.

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Synthesis and Characterization of Ru(II)−NSHC Catalysts Bearing Thiamine Analogs in Water‐Solvent Transfer Hydrogenation Catalysis

Kılınçarslan,

Menderes,

Tuncer

et al. 2024

Eur J Inorg Chem

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“Perfect match” of the carbazole-based conducting polymer and polyoxometalate nanocomposite components for enhanced optical and electrical properties

Güzel

Torlak

Choi

et al. 2023

European Polymer Journal

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N-alkylbenzimidazolepalladium(II) complexes: Synthesis and their catalytic activities in direct C-H functionalization of pyrrole, furan and 2-acetylthiophene

Ciçek,

Ispir,

Ozdemir

et al. 2024

Journal of Organometallic Chemistry

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N,S-heterocyclic carbene containing benzothiazol-2-ylidene-Ru(II) and Pd(II) new complexes functionalized with butyl linked carbazole moiety: Synthesis, characterization and their catalytic efficiency and electropolymerizations

Cited by 7 publications

References 103 publications

Synthesis and Characterization of Ru(II)−NSHC Catalysts Bearing Thiamine Analogs in Water‐Solvent Transfer Hydrogenation Catalysis

Synthesis and Characterization of Ru(II)−NSHC Catalysts Bearing Thiamine Analogs in Water‐Solvent Transfer Hydrogenation Catalysis

“Perfect match” of the carbazole-based conducting polymer and polyoxometalate nanocomposite components for enhanced optical and electrical properties

N-alkylbenzimidazolepalladium(II) complexes: Synthesis and their catalytic activities in direct C-H functionalization of pyrrole, furan and 2-acetylthiophene

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