In the field of thermal energy storage,
organic phase change materials
(PCMs) are widely used as functional materials to boost thermal applications.
However, there is often a tradeoff between constructing shape-stable
composite PCMs with high enthalpy value and those with low leakage
rates. Here, we proposed a promising scheme to address this issue.
A novel hydrogel consisting of reduced graphene oxide (rGO) and covalent
organic framework (COF) was prepared via hydrothermal methods, and
the rGO–COF ultralight aerogel with a hierarchical porous structure
was formed after freeze-drying. The rGO–COF aerogel shows excellent
absorption ability and affinity for organic solvents. It can sufficiently
adsorb the molten organic PCMs, such as polyethylene glycol (PEG),
and synthesize shape-stable composite PCMs with excellent leak resistance.
The COF grown on the surface of rGO has a superior affinity for PEG,
so rGO–COF aerogel shows an outstanding PEG loading rate of
up to 96.1 wt %, which is 1.7 wt % higher than that of rGO aerogel.
In addition, the COF effectively reduces the subcooling of PEG/rGO–COF
with 20.3%, compared to PEG/rGO. Meanwhile, the prepared PEG/rGO–COF
exhibits extremely high enthalpy and relative enthalpy efficiency
(164.6 J/g, 97.4%). This demonstrates that a promising direction was
highlighte for the preparation of high-enthalpy shape-stable composite
organic PCMs in this work.