2003
DOI: 10.1016/s0378-7753(03)00131-9
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Nano-particle Li4Ti5O12 spinel as electrode for electrochemical generators

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Cited by 191 publications
(93 citation statements)
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“…[ 51 ] The initial charge-discharge profi les for the Li 4 Ti 5 O 12 , Li 4 Ti 5 O 12 -TiO 2 , and Li 4 Ti 5 O 12 -TiO 2 -C nanocomposite electrodes at the 0.5 to 10 C charge/discharge rates are shown in Figure 6 (a-c) . Initial discharge capacities were measured to be 147, 167, and 166 mAh g − 1 at 0.5 C for the Li 4 12 -TiO 2 -C electrodes, respectively. The discharge capacity decreases for all samples with increasing current density, and some irreversible capacity loss was observed in the fi rst cycle, which might be due to irreversible electrochemical decomposition of the electrolyte or impurity phase over the Li 4 Ti 5 O 12 /TiO 2 surface.…”
Section: Full Papermentioning
confidence: 99%
“…[ 51 ] The initial charge-discharge profi les for the Li 4 Ti 5 O 12 , Li 4 Ti 5 O 12 -TiO 2 , and Li 4 Ti 5 O 12 -TiO 2 -C nanocomposite electrodes at the 0.5 to 10 C charge/discharge rates are shown in Figure 6 (a-c) . Initial discharge capacities were measured to be 147, 167, and 166 mAh g − 1 at 0.5 C for the Li 4 12 -TiO 2 -C electrodes, respectively. The discharge capacity decreases for all samples with increasing current density, and some irreversible capacity loss was observed in the fi rst cycle, which might be due to irreversible electrochemical decomposition of the electrolyte or impurity phase over the Li 4 Ti 5 O 12 /TiO 2 surface.…”
Section: Full Papermentioning
confidence: 99%
“…In order to improve the electrochemical performance of the Li 4 Ti 5 O 12 anode, extensive works concentrated on forming nanoparticles [14][15][16][17], doping [18][19][20][21][22][23] with metal cations and composing with carbon or metal powders [21,[24][25][26][27][28][29]. The formation of nanoparticles can reduce the Li-ion diffusion path as well as provide a large contact area between the nanoparticles.…”
Section: -10mentioning
confidence: 99%
“…However, the power performance of Li 4 Ti 5 O 12 is greatly limited by its low electronic conductivity (ca. 10 −13 S cm −1 ) and moderate Li diffusion coefficient (10 −8 -10 −11 cm 2 s −1 ) [20][21][22][23][24]. In order to improve the electrochemical performance of the Li 4 Ti 5 O 12 anode, extensive works concentrated on forming nanoparticles [25][26][27][28], doping [29][30][31][32][33][34] with metal cations, and composing with carbon or metal powders [35,36].…”
Section: Introductionmentioning
confidence: 99%