Nanocelluloses have attracted much attention in both
academic and
industrial fields. However, nanocelluloses, including cellulose nanocrystals
and cellulose nanofibers, are generally produced by a “top-down”
strategy with tedious violent chemical reactions and energy-intensive
mechanical treatments. Fabrication of nanocellulose via facile and
green approaches with a low cost is always challenging and promising.
The digestion of grass by ruminants resembles the extraction processing
of nanocelluloses from plants. Herein, lignocellulose nanoparticles
(LCNPs) were extracted from cattle dung via facile filtration and
centrifugation separation methods, indicating that LCNPs occurred
naturally in cattle dung and were formed during digestion of grass.
LCNPs are mainly composed of lignin, cellulose, and hemicellulose
and possess an average diameter of ∼50 nm, high surface charge
of −36.2 mV, and outstanding water dispersity. LCNPs show excellent
Pickering emulsifying ability just as classic nanocellulose due to
their partial wettability with both oil and water phases. LCNP stabilized
Pickering emulsions were then employed as templates to prepare phase
change material (PCM) microcapsules with melamine-formaldehyde shells
to prevent leakage of PCM. The obtained PCM microcapsules display
good thermal stability, durability, high PCM core content of 88.9%
and phase change enthalpy of 214.3 J g–1, and are
promising for thermal energy storage and temperature regulation applications.
This study provides a sustainable approach to extract nanocellulose
as Pickering emulsifier and will facilitate the high-value-added utilization
of cattle dung.