Nanocrystalline MoO₃/Polymerized Dibromo‐EDOT as Hybrid Nanocomposite: Efficient Hole Transport Material for Solid‐State Dye‐Sensitized Solar Cells

Abstract

A hybrid inorganic−polymer hole‐transport material (HTM) exhibited good photovoltaic properties owing to the excellent combination of desirable characteristics of the organic and inorganic materials. Solution‐processed nanocrystalline MoO3 and conducting polymerized dibromo‐3,4‐ethylenedioxythiophene (EDOT) were mixed to develop a hybrid material, which was used in efficient solid‐state dye‐sensitized solar cells (ssDSSCs) as an HTM. Nanocrystalline MoO3 was prepared by a low‐temperature solution method, and the dibromo‐EDOT was prepared from commercially available EDOT by a conventional bromination method. The incorporation of MoO3 into a hybrid HTM significantly improved the device efficiency owing to its high charge transport mechanism and suppression of the recombination in the ssDSSCs. Furthermore, we examined the influence of the blend ratio of MoO3 and dibromo‐EDOT on the photovoltaic performance of the devices. Moreover, the ssDSSCs were characterized by electrochemical impedance spectroscopy and Tafel polarization analysis to examine the charge transfer kinetics. The improved performance of the ssDSSCs could be attributed to increased charge carrier collection by the hybrid HTM. The photovoltaic results revealed that the device fabricated with a hybrid HTM containing 0.2 wt% MoO3 showed the best efficiency.

Recent Advances in Selenophene-Based Materials for Organic Solar Cells

“…If the power conversion efficiency (PCE) can be a further breakthrough, it may be used in production practice as it has terrific application prospects. According to different device structures, organic solar cells can be divided into the following three types: homojunction organic solar cells [11][12][13][14], bulk heterojunction organic solar cells [15][16][17][18], and dye-sensitized nanocrystalline organic solar cells [19][20][21][22][23]. Among them, bulk heterojunction is a thin film composed of electron acceptor (A) materials and electron donor (D) materials.…”