Nanoengineered metal-organic framework for adsorptive and photocatalytic mitigation of pharmaceuticals and pesticide from wastewater

Syntheses, structures, and luminescence properties of five new coordination polymers based on 3-carboxy-1-(3′-carboxybenzyl)-2-oxidopyridinium and neutral ligands

“…5a, there are one Cd(II) cation, one L 2− anion, one phen ligand and one coordinated water molecule in the asymmetric unit of 5. Each Cd(II) cation is six-coordinated by three oxygen atoms (Cd(1)-O(1) = 2.2210 (13), Cd(1)-O(3) = 2.2818 (12), and Cd(1)-O(5) #1 = 2.2748(12) Å) from two different L 2− anions, one coordinated water molecule (Cd(1)-O(1W) = 2.3096(13) Å), and two nitrogen atoms (Cd(1)-N(2) = 2.3582 (14) and Cd(1)-N(3) = 2.3579( 14) Å) from one phen ligand, which displays a distorted octahedral geometry. The L 2− anions bridge the Cd(II) ions in a μ 2 -η 0 :η 1 :η 1 :η 1 :η 0 mode (mode II in Scheme 1) to yield a 1D zigzag chain (Fig.…”

“…Selected bond distances, angles and hydrogen bond parameters for compounds 1-5 are listed in Tables S1-S8. † 2.1715 (14) and Zn(1)-N(2) #1 = 2.1715(14) Å) from two 4,4′-bpy ligands, while Zn2 is four-coordinated with four oxygen atoms (Zn(2)-O(5) = 1.9413 (13), Zn(2)-O(5) #1 = 1.9413 (13), Zn(2)-O(2) #2 = 1.9667 (13) and Zn(2)-O(2) #3 = 1.9667(13) Å) from four L 2− anions. The L 2− anions adopt a μ 3η 1 :η 1 :η 1 :η 1 :η 0 coordination mode (mode III in Scheme 1).…”

“…It is necessary to develop technology for the rapid detection of pollutants in water. 13,14 In particular, CPs, as a kind of luminescent probe, have shown broad prospects in the identification and sensing of environmentally toxic substances in the past decade. [15][16][17][18] Compared with other traditional detection techniques, luminescent CPs have the advantages of low cost, easy operation, and high sensitivity and selectivity.…”

Application of Metal–Organic Framework in Diagnosis and Treatment of Diabetes

“…Currently, many different synthetic methods can be used to generate MOFs, depending on the framework and property requirements. Commonly used synthesis methods include hydrothermal/solvothermal synthesis [ 16 , 17 , 18 ], room-temperature synthesis, microwave-assisted synthesis [ 19 ], ultrasonic-assisted synthesis [ 20 , 21 ], mechanochemical synthesis [ 22 ], microfluidic synthesis [ 23 , 24 ], biomimetic mineralization [ 25 , 26 ], and so on ( Table 1 ).…”

Design of Novel Photoactive Modified Titanium Silicalites and Their Application for Venlafaxine Degradation under Simulated Solar Irradiation

“…Among the most promising technologies, photocatalysis stands out for its recent advances in contaminant removal [1][2][3][4] or hydrogen production. [5][6][7] With these applications in mind, semiconductor materials of diverse nature and composition have been designed, such as metal-organic frameworks, [3,7] metalcarbon composites, [2,8] g-C 3 N 4 composites, [5,9] or TiO 2 -based materials, [4,6] among others. The objectives to be achieved in the preparation of photocatalysts are the improvement of the energy conversion efficiency and photochemical stability, the expansion of the excitation spectral range toward the visible, and the development of simple and low-cost synthesis methodologies that are scalable at the industrial level.…”