2024
DOI: 10.1002/ange.202403834
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Nanogels with Metal‐Organic Cages as Functional Crosslinks

Chaolei Hu,
Kay Severin

Abstract: A dinuclear metal‐organic cage with four acrylate side chains was prepared by self‐assembly. Precipitation polymerization of the cage with N‑isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the gel matrix, endowing the nanogel with the capability to serve as a sorbent for chloride ions in water. Moreover, a heteroleptic cage with the drug abiraterone as co‐ligand was integrated into a nanogel. The addition of chloride ions induced a structural rearran… Show more

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