“…In most of the solar energy harvesting routes, such as solar cells and photocatalysts, semiconductors are the core components of the solar energy conversion devices based on the photo excitation of electrons and holes in semiconductors to absorb solar energy [7,[10][11][12]. In the field of PEC water splitting, the nanomaterials of low-cost semiconductor metal oxides such as ZnO (E g ≈ 3.3 eV), TiO 2 (band gap E g ≈ 3.2 eV), and Fe 2 O 3 (E g ≈ 2.4 eV) are of particular interest for photocatalysis base materials due to their excellent chemical stability, low cost, safe to environment, and potentially high conversion efficiency [6,[10][11][12][13][14][15][16][17][18][19][20]. However, the practically achieved solar energy conversion efficiency of PEC systems based on these semiconductors remains rather low.…”