A novel
process to synthesize plasmonic MoO3–X
nanosheets is demonstrated, in which MoS2 powders
suspended in ethanol/water are irradiated with pulses from
a femtosecond laser, resulting in simultaneous Coulomb explosion,
photoexfoliation, and oxidation. The oxidation process is found to
start with the formation of hydrogen-bonded molybdenum oxide (H
X
MoO3), followed by the release
of −OH2 groups to create oxygen vacancies, and finally,
MoO3–X
is oxidized to MoO3 after extended irradiation. The formation of H
X
MoO3 is the critical step to create enough oxygen
vacancies for localized surface plasmon resonance (LSPR), and this
step is attributed to H3
+ dissociated from ethanol
under femtosecond laser irradiation. It is found that 80–90%
ethanol is the optimal concentration to synthesize plasmonic MoO3–X
, where the balance of water facilitates
the release of the −OH2 groups to create the required
vacancies. It is shown that different organic solvents like methanol,
1-propanol, and isopropyl alcohol that were reported to generate large
amounts of H3
+ under femtosecond laser irradiation
can also oxidize MoS2 into plasmonic MoO3–X
. The LSPR properties of the synthesized MoO3–X
are evaluated by UV–vis
spectroscopy and photothermal conversion measurements. A photothermal
conversion efficiency of 33% is observed under near-infrared irradiation,
suggesting a potential application in photothermal cancer therapy.