Nanoparticle Mediated Improved Crystallinity and Connectivity of Semiconducting Polymer Thin Films

Abstract

Polymer nanocomposites (PNCs), i.e., nanoparticle (NP) incorporated semiconducting polymers (SPs), constitute a class of active materials where the dispersion and locations of the NPs and the crystallinity of the SPs play important roles in deciding their device performances. Herein Au nanoparticle (AuNP) mixed poly(3-hexylthiophene) [P3HT] was taken as a model PNC system, and a unique combination of complementary techniques was utilized to address these dispersion-related structural issues, viz the organization and/or dispersion of AuNPs, its evolution with thermal annealing (TA), and their effects on the ordering or crystallization of the P3HT matrix. The layering of AuNPs near the interfaces, namely confined or near monolayer thick layer at the film−substrate interface and fluctuated or near bilayer thick layer at the film−air interface, are evident in the as-cast PNC thin films, indicating self-organization and phase separation tendencies of the similar and dissimilar materials (i.e., dominant decrease of enthalpic energy over entropy) and different (hard and soft) boundary conditions of the interfaces. On the other hand, appreciable dispersion of AuNPs inside P3HT matrix is evident after TA, suggesting thermal energy induced diffusion of AuNPs through amorphous P3HT regions, overcoming the selforganization and phase separation (i.e., dominant increase of entropic energy over enthalpy). Such dispersion enhances the quantity (fraction or amount) and quality (planarity or conjugation length) of P3HT crystallites (and thus validates the dispersion of AuNPs in the amorphous P3HT regions) and their edge-on orientation and connectivity. This information or understanding is very useful for optimizing the structures of the PNC-based active layers for their better charge carrier mobility and device performances.

Molecular Dipole Layer and Alkyl Side-Chain Induced Improvement in the Energy Level Alignment and Wetting of Dinaphthothienothiophene Thin Films

“…At the same time, unconventional organic semiconductors are also becoming quite important due to their unique capabilities to form large-scale and flexible devices through easy processing. Extensive research is going on with these materials − in the form of organic thin-film transistors, − organic photovoltaics, , and organic light-emitting diodes for their potential applications in electronic and optoelectronic industries as well as in medical devices . Although these materials are very promising for future electronic and optoelectronic devices, there are some issues with these kinds of materials like low charge carrier mobility, poor environmental stability, and so on.…”