“…First, the combination of fluorescent core–shell SiP deposition and binary silanization increased the stability of the water repellency compared to other methodologies. ,, Our methodology uses fluorine-free polymers at low concentrations (approximately 4%) and solvents with low toxicity potential (e.g., water and ethanol). ,,, In addition, the fluorescent core–shell SiPs were used as fluorescent probes to facilitate the coating detection on the surface of the fibers. By tuning the type of molecule being encapsulated into the core–shell, the fibers can be designed to be luminescent, antimicrobial, or insect repellent, to name a few. ,,− In this way, the fluorescent core–shell SiPs produced in this work can act as a robust and multifunctional platform to provide hydrophobicity, corrosion resistance, and self-cleaning properties to the cotton fibers. ,, Finally, they can also be tuned to work as antimicrobial, antisticking, oil–water separation, and insect repellent agents for a myriad of applications. , …”