Owing to the advancement of security technologies, several
encryption
methods have been proposed. Despite such efforts, forging artifices
is financially and somatically becoming a constraint for individuals
and society (e.g., imprinting replicas of luxury goods or directly
life-connected medicines). Physically unclonable functions (PUFs)
are one of the promising solutions to address these personal and social
issues. The unreplicability of PUFs is a crucial factor for high security
levels. Here, this study proposes a visually hidden and self-assembled
porous polymer (VSPP) as a tag for optical PUF systems. The VSPP has
virtues in terms of wavelength dependency, lens-free compact PUF system,
and simple/affordable fabrication processes (i.e., spin coating and
annealing). The VSPP consists of an external saturated surface, which
covers the inner structures, and an internally abundant porous layer,
which triggers stochastic multiple Mie scattering with wavelength
dependency. We theoretically and experimentally validate the unobservability
of the VSPP and the uniqueness of optical responses by image sensors.
Finally, we establish a wavelength-dependent PUF system by using the
following three components: solid-state light sources, a VSPP tag,
and an image sensor. The captured raw images by the sensor serve as
“seed” for unique bit sequences. The robustness of our
system is successfully confirmed in terms of bit uniformity (∼0.5),
intra/interdevice Hamming distances (∼0.04/∼0.5), and
randomness (using NIST test).