Resonantly enhanced emission from the zero-phonon line of a diamond nitrogen-vacancy (NV) center in single crystal diamond is demonstrated experimentally using a hybrid whispering gallery mode nanocavity. A 900 nm diameter ring nanocavity formed from gallium phosphide, whose sidewalls extend into a diamond substrate, is tuned onto resonance at a low temperature with the zero-phonon line of a negatively charged NV center implanted near the diamond surface. When the nanocavity is on resonance, the zero-phonon line intensity is enhanced by approximately an order of magnitude, and the spontaneous emission lifetime of the NV is reduced by as much as 18%, corresponding to a 6.3X enhancement of emission in the zero photon line. DOI: 10.1103/PhysRevX.1.011007 Subject Areas: Nanophysics, Photonics, Quantum InformationThe diamond nitrogen-vacancy (NV) center is an optically active impurity which combines many of the desirable properties of quantum dots and laser-trapped atoms. Optical transitions of diamond NV centers can display low inhomogeneous broadening, and have been used to generate single photons [1], manipulate single electron spins [2], and control nearby nuclear spin impurities [3][4][5]. Remarkably, the room temperature electron spin coherence times of NVs can exceed a millisecond [6]. These properties make NVs a promising qubit for proposed quantum networks [7], and an attractive system for applications such as magnetometry [8] and low power optical switching [9]. An outstanding challenge limiting the use of NV centers as qubits in quantum information processing is the creation of a platform for mediating interactions between them. A promising approach to this problem is to create an onchip quantum network in which NVs interact optically via nanophotonic interconnects [10]. Coupling NVs to optical cavities plays a crucial role in this implementation by enhancing the NV emission into a well-defined optical mode, which can be efficiently coupled to waveguides and routed on-chip. Cavity enhancement of the emission is particularly important for NV centers, as it provides a means for increasing the relative brightness of the narrowband zero-phonon line (ZPL) emission relative to the broadband phonon assisted emission. The selection of the emission into the ZPL is necessary for protocols involving coherent interactions or indistinguishable photons.Demonstrating diamond-based quantum networks has recently prompted significant research into integrating NV centers with photonic devices [11]. Efforts to efficiently couple NVs in nanocrystalline diamond to nanophotonic structures [12][13][14][15] have been limited by poor NV optical properties in nanocrystals compared to those found in single crystal diamond. Fabricating nanophotonic devices directly from single crystal diamond has recently made important progress [11,16,17], limited primarily by fabrication difficulties related to creating thin films of single crystal diamond necessary for optical confinement in three dimensions. An alternative approach, which levera...