“…[1][2][3] The use of chemically active nitrogen or oxygen as a working gas in the vacuum chamber allows the synthesis of various nitride [4,5] or oxide coatings [6,7] and their mixtures. [8,9] Thin-film coatings based on titanium nitride are characterized by high wear resistance, [10] high corrosion resistance, [11] high evaporation temperature, chemical stability, [12] and other crucial characteristics, [13] leading to the wide application of these coatings in microelectronics, [14] optics, [15] and other industries. Titanium dioxide is an important coating material, providing protection to the underlying substrate from undesirable effects of aggressive media or irradiation by electrons and ions [16][17][18][19] on structural materials.…”