Membrane
biofouling is a major stumbling block in membrane technology
and particularly in the water treatment industry. Biofouling, in particular,
is a serious concern because it is irreversible and thus cuts the
lifespan of the polymeric membranes. This review, therefore, explores
the fundamentals of biofouling development and the factors that promote
biofilm growth in polymeric membrane systems. In this pursuit, we
discuss avenues through which antibiofouling polymeric membranes have
been fabricated using inorganic and carbon-based nanomaterials as
membrane nanofillers to enhance the hydrophilicity and antibiofilm
properties of the resultant composite membranes without significantly
compromising the membrane filtering abilities. We further elucidate
the chemistry by which the membrane nanofillers mitigate or inhibit
the formation and growth of the undesirable biofilms on the surface
and pores of the membranes. In achieving this, recent works on polymeric
membrane biofouling are reviewed, with a particular focus on the correlation
between the membrane performance and the physicochemical properties
of the filler nanomaterials. The merits and demerits of inorganic
and carbon-based nanomaterials as fillers to confer an antibacterial
effect to the membranes are presented and perspectives and opinions
on the future direction of biofouling mitigation in membranes are
outlined.