Nanoscale zinc-based metal-organic framework with high capacity for lithium-ion batteries

Shi, Chengcheng; Gao, Yuanrui; Liu, Huan; Song, Yidan; Wang, Xianmei; Liu, Hongjiang; Liu, Qi

doi:10.1007/s11051-016-3641-5

Cited by 27 publications

(19 citation statements)

References 49 publications

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“…The good cycling performance of this Zn-based CP comes from (1) multi-redox active sites including Zn(II) and conjugated carboxylates from mpca and tfbdc ligands; (2) flexible 1D chains, which provide shorter Li ions diffusion space; and (3) the reversible transformation and regeneration of CP structure. Additionally, similar battery reaction principles have been used to explain the case of Co3(HCOO)6, 86 Mn−LCP (Mn(tfbdc)(4,4′bpy)(H2O)2), 88 Cu-BDC [Cu2(C8H4O4)4]n, 89 Ni-Me4bpz ([H2Me4bpz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole], 90 Zn-LMOF (Zn(4,4′-bpy)(tfbdc)(H2O)2), 91 Co-LCP (Co(tfbdc)(4,40bpy)(H2O)2), 92 and CoCOP (polycarboxylate-Co coordination polymer). 93…”

Section: Conversion-type Reactionmentioning

confidence: 99%

“…25 There are many present forms of metal nodes in redox-MOPs, including mono-valent alkali metal ions, multi-valent transitional metal ions, mix-valent metal ions, and mixed-kinds metal ions, and so on. 15,16,84,91,111,118,[134][135][136][137][138][139][140][141] Thus, it's necessary to discuss the possible choice of metal nodes in order to lay a foundation for future research. Considering that other sections mainly focus on the analysis of multi-valent metal nodes, the following paragraph will switch to those redox-MOPs characterized by ( 1) mono-valent metal ions and (2) mixed-kinds metal ions.…”

Section: Substitution and Optimization Of Metal Nodesmentioning

confidence: 99%

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Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

et al. 2019

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Section: Conversion-type Reactionmentioning

confidence: 99%

Section: Substitution and Optimization Of Metal Nodesmentioning

confidence: 99%

Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

et al. 2019

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“…The cycling stability and the rate performance of this kind of tfbdc and 4,4′‐bpy built layered MOFs were further improved by reducing the particle size to nanoscale by the same group. They prepared [Zn(tfbdc)(4,4′‐bpy)(H 2 O) 2 ] nanosheets with thickness of 24 ± 8 nm, showing an enhanced capacity of 632 mA h g −1 after 100 cycles along with excellent cycling stability and high rate performance …”

Section: Li‐based Batteriesmentioning

confidence: 99%

Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion

et al. 2017

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Metal-organic frameworks (MOFs), a new class of crystalline porous organic-inorganic hybrid materials, have recently attracted increasing interest in the field of energy storage and conversion. Herein, recent progress of MOFs and MOF composites for energy storage and conversion applications, including photochemical and electrochemical fuel production (hydrogen production and CO reduction), water oxidation, supercapacitors, and Li-based batteries (Li-ion, Li-S, and Li-O batteries), is summarized. Typical development strategies (e.g., incorporation of active components, design of smart morphologies, and judicious selection of organic linkers and metal nodes) of MOFs and MOF composites for particular energy storage and conversion applications are highlighted. A broad overview of recent progress is provided, which will hopefully promote the future development of MOFs and MOF composites for advanced energy storage and conversion applications.

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“…This effective ion transportation in the MON based anodes resulted in 100% coulombic efficiency, outstanding rate capability, and long-term cyclic performance-key performance parameters in LIBs. [158][159][160] MONs have also been used in conjunction with conductive supports to form high performing hybrid electrodes. Yao c) Reproduced with permission.…”

Section: Electrodes For Energy Storagementioning

confidence: 99%

Metal–Organic Framework Nanosheets: Programmable 2D Materials for Catalysis, Sensing, Electronics, and Separation Applications

Nicks¹,

Sasitharan²,

Prasad³

et al. 2021

Adv Funct Materials

117

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offers advantages over simple inorganic nanosheets in that a diverse range of physical and chemical properties can be programmed into their crystalline structure (Figure 1). This distinct combination of properties makes MONs ideal for a wide range of catalysis, sensing, electronics, and separation applications which will be the focus of this review.Much of the early literature in this field focused on the development of novel MON architectures and new routes towards their synthesis. A diverse range of different metal ions and organic linkers have been used to construct MONs. [4] However the field has rapidly converged on a handful of popular secondary building units (SBUs) which dominate much of the literature thanks to their reliable formation of high aspect ratio nanosheets. Popular classes of MONs that have been widely applied by different groups in applications include those based on the metal paddlewheel (PW) motif, [5][6][7] axially capped Zr and Hf clusters, [8][9][10][11] 2D zeolitic imidazolate frameworks (ZIFs), [12][13][14] and square planar Ni, Co, and Cu SBUs. [15][16][17][18] The modular structure of MONs, ease of functionalization and diverse range of materials they can be combined with means that MONs can be readily "programmed" to provide the desired topology and properties required for a given application.A wide variety of methods have been explored to synthesize MONs, either "top-down" by the exfoliation of layered metalorganic frameworks (MOFs) or "bottom-up" by assembly of molecular building blocks directly into nanosheets. The majority of top-down approaches utilize mechanical energy to overcome inter-layer interactions, such as liquid-assisted ultrasonication, [19] shear-mixing, [20] and grinding/ball-milling, [13] or the less common freeze-thaw [21] and "scotch-tape" methods. [22,23] Other methods involving photochemical, [24] electrochemical, [25] and chemical intercalation, [26] have also been developed but are less widely used. Bottom-up methodologies typically utilize surfactants or modulators to inhibit crystal growth in one dimension, [12,27,28] or layering/interfacial methods to promote anisotropic growth. [15,29,30] The use of sacrificial 2D templates has also recently emerged a promising route. [31,32] Each approach has advantages and disadvantages in terms of the thickness, lateral dimensions, size distribution, quantity and quality of the MONs produced, and the best approach therefore varies depending on the application.

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Nanoscale zinc-based metal-organic framework with high capacity for lithium-ion batteries

Cited by 27 publications

References 49 publications

Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries

Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion

Metal–Organic Framework Nanosheets: Programmable 2D Materials for Catalysis, Sensing, Electronics, and Separation Applications

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