Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103

Callini, Elsa; Aguey‐Zinsou, Kondo‐François; Ahuja, Rajeev; Ares, J.R.; Bals, Sara; Biliškov, Nikola; Chakraborty, Sudip; Charalambopoulou, Georgia; Chaudhary, Anna‐Lisa; Cuevas, Fermín; Dam, B.; Jongh, Petra E. de; Dornheim, Martin; Filinchuk, Yaroslav; Novaković, Jasmina Grbović; Hirscher, Michael; Jensen, Torben R.; Jensen, Peter Bjerre; Novaković, Nikola; Lai, Qiwen; Leardini, Fabrice; Gattia, Daniele Mirabile; Pasquini, Luca; Steriotis, Theodore; Turner, Stuart; Vegge, Tejs; Züttel, Andreas; Montone, A.

doi:10.1016/j.ijhydene.2016.04.025

Cited by 104 publications

(54 citation statements)

References 190 publications

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“…with results of other large car companies [2], the problem of the effective and safe hydrogen on-board storage has yet been under consideration of a number of scientists, for instance, [6]- [12].…”

Section: On Solving the Current Problem Of The Effective And Safe Hydmentioning

confidence: 99%

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Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

Nechaev¹,

Makotchenko²,

Shavelkina³

et al. 2017

OJEE

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It presented a comparative consideration of General Motors long-term activities on the current subject of fuel-cell-powered electric vehicles vs Toyota Mirai recent results, relevant to prospects on more efficient and safe technologies of the hydrogen on-board storage. It also presented a call on the project International cooperation. The main aim of this paper is to attract attention of General Motors, Toyota and/or other large car companies to a real possibility of developing and using, in the nearest future, of the break-through hydrogen on-board storage technology based on the solid H 2 intercalation into graphite nanostructures.

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Section: On Solving the Current Problem Of The Effective And Safe Hydmentioning

confidence: 99%

“…It is related to the current unresolved problems of the clean energy, including the problem of a compact and safe storage of hydrogen in eco-cars [6]- [17].…”

Section: Synopsis Of the International Research Project "Thermodynamimentioning

confidence: 99%

Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

Nechaev¹,

Makotchenko²,

Shavelkina³

et al. 2017

OJEE

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“…Falling into this category is a newer method, which is cryoadsorption. It is based on the storage of H 2 by liquefaction (at liquid‐N 2 temperature, −196 °C) in the porosity of scaffold‐like metal–organic frameworks and polymers with intrinsic porosity . The second category of the storage methods is chemical H storage.…”

Section: Introductionmentioning

confidence: 99%

“…It is based on the storage of H 2 by liquefaction (at liquid-N 2 temperature, À196 8C) in the porosity of scaffoldlike metal-organic frameworks and polymers with intrinsic porosity. [7,8,10,11] Thes econd category of the storage methods is chemical Hs torage. It is based on chemical bonding between ap referably light heteroelement and atomic hydrogen and on the breaking of the bond towards the formation of H 2 through intra-/intermolecular reactions.…”

Section: Introductionmentioning

confidence: 99%

About the Technological Readiness of the H₂ Generation by Hydrolysis of B(−N)−H Compounds

Demirci

2018

Energy Tech

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At the beginning of the new millennium, hydrolysis of sodium borohydride (NaBH4) was presented as a promising on‐board technology to generate H2 for light‐duty vehicles. Years later, other B(−N)−H compounds (e.g., lithium borohydride (LiBH4) and ammonia borane (NH3BH3)) emerged as attractive alternatives whereas NaBH4 was struggling with several issues jeopardizing its implementation. Actually, efforts in the research and development of H2 generation by hydrolysis of B(−N)−H compounds have been intensive since the advent of NaBH4 almost 20 years ago. There may be a question with respect to this: What is the technological readiness of the promising hydrolytic B(−N)−H compounds? This Review aims at providing relevant elements in response to this question. In the first part, the most mature B(−N)−H compounds are discussed at length. In the second part, a survey of all other candidates is proposed. It is concluded that NaBH4 is the best hydrolytic B(−N)−H compound for marketing on a broad scale, but there are still key challenges to address.

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“…By storing hydrogen in the liquid state, one attains a high volumetric density (70 g/L), but the low liquid-vapour equilibrium temperature (20 K at standard pressure) is an important obstacle for its use because of the high energy requirements for liquefaction and the remarkable boil-off losses. Many of the practical issues of these two methods are solved by storing hydrogen in a solid framework, which is able to adsorb hydrogen [2][3][4]. In this case, there are two possible mechanisms of adsorption: chemisorption, according to which a reversible chemical reaction occurs between the solid substrate material and molecular hydrogen, causing the dissociation of the hydrogen molecule and the formation of a new compound, typically a metal or complex hydride; and physisorption, according to which the diatomic molecule does not dissociate and its bond with the solid framework is realized by means of van der Waals interaction.…”

Section: Introductionmentioning

confidence: 99%

Ice XVII as a Novel Material for Hydrogen Storage

2017

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Hydrogen storage is one of the most addressed issues in the green-economy field. The latest-discovered form of ice (XVII), obtained by application of an annealing treatment to a H 2 -filled ice sample in the C 0 -phase, could be inserted in the energy-storage context due to its surprising capacity of hydrogen physisorption, when exposed to even modest pressure (few mbars at temperature below 40 K), and desorption, when a thermal treatment is applied. In this work, we investigate quantitatively the adsorption properties of this simple material by means of spectroscopic and volumetric data, deriving its gravimetric and volumetric capacities as a function of the thermodynamic parameters, and calculating the usable capacity in isothermal conditions. The comparison of ice XVII with materials with a similar mechanism of hydrogen adsorption like metal-organic frameworks shows interesting performances of ice XVII in terms of hydrogen content, operating temperature and kinetics of adsorption-desorption. Any application of this material to realistic hydrogen tanks should take into account the thermodynamic limit of metastability of ice XVII, i.e., temperatures below about 130 K.

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Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103

Cited by 104 publications

References 190 publications

Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

About the Technological Readiness of the H₂ Generation by Hydrolysis of B(−N)−H Compounds

Ice XVII as a Novel Material for Hydrogen Storage

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Nanostructured materials for solid-state hydrogen storage: A review of the achievement of COST Action MP1103

Cited by 104 publications

References 190 publications

Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies

About the Technological Readiness of the H2 Generation by Hydrolysis of B(−N)−H Compounds

Ice XVII as a Novel Material for Hydrogen Storage

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Product

Resources

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About the Technological Readiness of the H₂ Generation by Hydrolysis of B(−N)−H Compounds