Nanostructured rhodium: electrochemical behaviour and electrodeposition from low‐temperature carbamide‐ and acetamide‐containing melts

Abstract

It was ascertained that in carbamide-and acetamide-chloride melts at anodic dissolution of rhodium some mixed complexes [Rh(NH 3 ) 4 Cl 2 ] + form which are of quasioctahedral structure and D4h symmetry. During cathodic reduction of the obtained complexes Rh(III) in the investigated melts the synthesis of nanoparticles Rh was carried out as well as nanocoating of Fe, Cu and Mo by them.