Nowadays, the materials commonly used to fabricate thermoelectric devices are tellurium, lead and germanium. These materials ensure from one side the best thermoelectric performances, but exhibit drawbacks in terms of availability, sustainability, cost and manufacturing complexity. Moreover, they do not guarantee a safe and cheap implementation in wearable thermoelectric applications. Here, p-and n-type flexible thermoelectric textiles are produced with sustainable and low-cost materials through green and scalable processes. Cotton is functionalized with inks made with biopolyester and carbon-nanomaterials. Depending on the nanofiller, i.e. graphene nanoplatelets, carbon nanotubes or carbon nanofibers, positive or negative Seebeck coefficient values are obtained, achieving also a remarkable value of electrical conductivity of 55 S cm -1 using carbon nanotubes. The best bending and washing stability are registered for the carbon nanofibers-based biocomposites, which increase their electrical resistance by 5 times after repeated bending cycles and only of the 30% after washing. Finally, in-plane flexible thermoelectric generators are fabricated and characterized coupling the best p-and n-type materials, achieving an output voltage of ~ 1.65 mV and a maximum output power of ~ 1.0 nW by connecting only 2 p/n thermocouples at a temperature difference of 70°C.