2022
DOI: 10.1002/idm2.12044
|View full text |Cite
|
Sign up to set email alerts
|

NaSICON: A promising solid electrolyte for solid‐state sodium batteries

Abstract: A surge of interest has been brought to all-solid-state batteries (ASSBs) as they show great prospects for enabling higher energy density and improved safety compared to conventional liquid batteries. Na Super Ionic CONductors (NaSICONs) proposed by Goodenough and Hong in 1976 are the most promising materials class for Nabased ASSBs owing to their excellent ion conductivity (>1 mS cm −1 ), high thermal and chemical/electrochemical stability, as well as good chemical/electrochemical compatibility with electrode… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

0
55
0

Year Published

2023
2023
2024
2024

Publication Types

Select...
9

Relationship

0
9

Authors

Journals

citations
Cited by 80 publications
(55 citation statements)
references
References 144 publications
0
55
0
Order By: Relevance
“…NaSICON is a fast Na + conductor discovered by Hong and Goodenough in 1976 . Na + is transported through the bottlenecks created by corner-sharing zirconia octahedra and silica tetrahedra. , NaSICON synthesis was achieved using solid-state ceramic processing techniques described by Gross et al ZrSiO 4 (Sigma-Aldrich, −325 mesh), Na 3 PO 4 ·12H 2 O (Sigma-Aldrich, >98%), SiO 2 (Sigma-Aldrich), and NaCO 3 (Fisher Scientific) powders were ball-milled in ethanol in a 2:0.6:0.4:0.8 molar ratio and subsequently dried by rotary evaporation before further drying under vacuum overnight. The resulting NaSICON precursor powder was calcined at 600 °C for 12 h in air.…”
Section: Methodsmentioning
confidence: 99%
“…NaSICON is a fast Na + conductor discovered by Hong and Goodenough in 1976 . Na + is transported through the bottlenecks created by corner-sharing zirconia octahedra and silica tetrahedra. , NaSICON synthesis was achieved using solid-state ceramic processing techniques described by Gross et al ZrSiO 4 (Sigma-Aldrich, −325 mesh), Na 3 PO 4 ·12H 2 O (Sigma-Aldrich, >98%), SiO 2 (Sigma-Aldrich), and NaCO 3 (Fisher Scientific) powders were ball-milled in ethanol in a 2:0.6:0.4:0.8 molar ratio and subsequently dried by rotary evaporation before further drying under vacuum overnight. The resulting NaSICON precursor powder was calcined at 600 °C for 12 h in air.…”
Section: Methodsmentioning
confidence: 99%
“…https://mc03.manuscriptcentral.com/jacer 3 NASICON (Na superionic conductor)-structured compounds are interesting materials that can be used as solid electrolytes as well as cathodes in secondary batteries [14][15][16][17][18][19][20][21]. Particularly, NASICON compounds proposed by Hong and Goodenough, which have the formula Na1+xZr2SixP3−xO12 (0 ≤ x ≤ 3), exhibit Na + ion conductivities in the order of 10 −4 S cm −1 and have wide electrochemical windows; these properties make them suitable for use as solid electrolytes in Na-based batteries.…”
Section: Journal Of Advanced Ceramicsmentioning
confidence: 99%
“…Although Na + ion conducting NaSICON materials were discovered more than 50 years ago [1][2][3] and have been intensively studied in recent years, [4][5][6][7][8][9][10][11][12] the examined compositional range of NaSICONs is still limited, and a thorough understanding of Na + ion transport seems to be lacking.…”
Section: Introductionmentioning
confidence: 99%
“…13,[17][18][19][49][50][51][52] Various review articles summarize the developments and challenges of NaSICON materials for all-solid-state NIBs. [4][5][6][7][8][9][10][11][12] NaSICON structures with the general formula Na x M 2 (AO 4 ) 3 , exhibit a exible framework in which various M and A cations can be incorporated. Therefore, they offer a large compositional diversity allowing a wide range of applications, but also leading to ionic conductivities that vary over orders of magnitude.…”
Section: Introductionmentioning
confidence: 99%