NaSICON-type materials for lithium-ion battery applications: Progress and challenges

Xiao, Jingwen; Zhang, Bao; Liu, Junxiang; He, Xinyou; Xiao, Zhiming; Qin, Haozhe; Liu, Tongchao; Amine, Khalil; Ou, Xing

doi:10.1016/j.nanoen.2024.109730

Nano Energy

2024

DOI: 10.1016/j.nanoen.2024.109730

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NaSICON-type materials for lithium-ion battery applications: Progress and challenges

Jingwen Xiao,

Bao Zhang,

Junxiang Liu

et al.

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Cited by 13 publications

References 181 publications

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Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives

Huang,

Li,

Jiang

et al. 2024

Adv Funct Materials

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The use of all‐solid‐state lithium metal batteries (ASSLMBs) has garnered significant attention as a promising solution for advanced energy storage systems. By employing non‐flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the use of lithium metal as the anode allows for higher energy density compared to traditional lithium‐ion batteries. To fully realize the potential of ASSLMBs, solid‐state electrolytes (SSEs) must meet several requirements. These include high ionic conductivity and Li+ transference number, smooth interfacial contact between SSEs and electrodes, low manufacturing cost, excellent electrochemical stability, and effective suppression of dendrite formation. This paper delves into the essential requirements of SSEs to enable the successful implementation of ASSLMBs. Additionally, the representative state‐of‐the‐art examples of SSEs developed in the past 5 years, showcasing the latest advancements in SSE materials and highlighting their unique properties are discussed. Finally, the paper provides an outlook on achieving balanced and improved SSEs for ASSLMBs, addressing failure mechanisms and solutions, highlighting critical challenges such as the reversibility of Li plating/stripping and thermal runaway, advanced characterization techniques, composite SSEs, computational studies, and potential and challenges of ASS lithium–sulfur and lithium–oxygen batteries. With this consideration, balanced and improved SSEs for ASSLMBs can be realized.

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Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives

Huang,

Li,

Jiang

et al. 2024

Adv Funct Materials

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Metal–Organic Coordination Enhanced Metallopolymer Electrolytes for Wide‐Temperature Solid‐State Lithium Metal Batteries

Zhao,

Wang,

Huang

et al. 2024

Angewandte Chemie

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The practical application of polymer electrolytes is seriously hindered by the inferior Li+ ionic conductivity, low Li+ transference number (tLi+), and poor interfacial stability. Herein, a structurally novel metallopolymer is designed and synthesized by exploiting a molybdenum (Mo) paddle‐wheel complex as a tetratopic linker to bridge organic and inorganic moieties at molecular level. The prepared metallopolymer possesses combined merits of outstanding mechanical and thermal stability, as well as a low glass transition temperature (Tg < –50 °C). Based on this metallopolymer, an advanced metal‐organic coordination enhanced metallopolymer electrolyte (MPE) is developed for constructing high‐performance solid‐state lithium metal batteries (LMBs). Due to the unsaturated coordination of Mo atoms, the uniformly distributed Mo‐polyoxometalates (Mo‐POMs) in metallopolymer skeleton can effectively bis(fluorosulfonyl)imide anions (FSI‐) and promote the dissociation of Li salts. Moreover, dynamic metal‐organic coordination bonds endow the MPE with re‐processability and self‐healing, enabling it to accommodate electrode volume changes and maintain good interfacial contact. Consequently, the MPE achieves a competitive ionic conductivity of 0.712 mS cm‐1 (25 °C), a high tLi+ (0.625), and a wide electrochemical stability window (> 5.0 V). This study presents a unique MPE design based on metal‐organic coordination enhanced strategy, providing a promising solution for developing wide‐temperature solid‐state LMBs.

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Metal–Organic Coordination Enhanced Metallopolymer Electrolytes for Wide‐Temperature Solid‐State Lithium Metal Batteries

Zhao,

Wang,

Huang

et al. 2024

Angew Chem Int Ed

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NaSICON-type materials for lithium-ion battery applications: Progress and challenges

Cited by 13 publications

References 181 publications

Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives

Solid‐State Electrolytes for Lithium Metal Batteries: State‐of‐the‐Art and Perspectives

Metal–Organic Coordination Enhanced Metallopolymer Electrolytes for Wide‐Temperature Solid‐State Lithium Metal Batteries

Metal–Organic Coordination Enhanced Metallopolymer Electrolytes for Wide‐Temperature Solid‐State Lithium Metal Batteries

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