Silicone materials are used in a wide variety of
consumer/industrial products and process aids. Disposal
to wastewater treatment is the primary source of entry for
silicones (primarily poly(dimethylsiloxane) or PDMS) in
aquatic environments. However, limited information
is available on the concentration ranges, distribution, and
fate of silicone materials in surface sediments. In this
study, PDMS was measured in the surface sediments of
four marine and four freshwater areas heavily impacted by
municipal wastewater discharge to illustrate worst-case
situations for the United States. Concentrations of PDMS
were measured in 12−14 samples from each study area.
Measured dry weight concentrations of PDMS ranged
from below detection (0.2 μg·g-1) to 309 μg·g-1. Low level
concentrations (≤0.6 μg·g-1) that were measured in
25% of the sediments may have been natural silicon
materials rather than PDMS. Generally, concentrations of
PDMS were greatest in sediments from depositional
areas near effluent outfalls. Mean concentrations of PDMS
(±SE) ranged from 0.6 ± 0.1 to 78 ± 20 μg·g-1 and
were lowest in areas having advanced levels of wastewater
treatment. Concentrations of PDMS in these “worst-case” sediments were less than the “no observable effects
concentration” (NOEC) established in laboratory studies
using sediment-dwelling organisms.