Natural and Synthetic Polymers Modified with Acid Blue 113 for Removal of Cr3+, Zn2+ and Mn2+

Marin, Nicoleta Mirela

doi:10.3390/polym14112139

Cited by 11 publications

(9 citation statements)

References 35 publications

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“…The calibration curve A = 0.0410 C − 0.2690 was used for the quantitative determination of DR 23, where C (mg/L) is the concentration of DR 23 in the supernatant solution. Additionally, the limit of determination (LD) was 0.73 mg/L DR 23 (corresponding to ten times of standard deviation of the blank solution measured at 507 nm) [18].…”

Section: Uv-vis Determination Of Dr 23mentioning

confidence: 99%

New Chelate Resins Prepared with Direct Red 23 for Cd2+, Ni2+, Cu2+ and Pb2+ Removal

et al. 2022

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In this paper, two chelate resins prepared by a simple procedure were used for the removal of Cd2+, Ni2+, Cu2+, and Pb2+ (M2+) from aqueous solutions. Amberlite IRA 402 strongly basic anion exchange resin in Cl− form (IRA 402(Cl−) together with Amberlite XAD7HP acrylic ester co-polymer (XAD7HP) were functionalized with chelating agent Direct red 23 (DR 23). The chelate resins (IRA 402-DR 23 and XAD7HP-DR 23) were obtained in batch mode. The influence of interaction time, pH and the initial concentration of DR 23 solution was investigated using UV-Vis spectrometry. The time necessary to reach equilibrium was 90 min for both resins. A negligible effect of adsorption capacity (Qe) was obtained when the DR 23 solution was adjusted at a pH of 2 and 7.9. The Qe of the XAD7HP resin (27 mg DR 23/g) is greater than for IRA 402(Cl−) (21 mg DR 23/g). The efficiency of chelating resins was checked via M2+ removal determined by the atomic adsorption spectrometry method (AAS). The M2+ removal by the IRA 402-DR 23 and XAD7HP-DR 23 showed that the latter is more efficient for this propose. As a consequence, for divalent ions, the chelated resins followed the selectivity sequence: Cd2+ > Cu2+ > Ni2+ > Pb2+. Additionally, Cd2+, Cu2+ and Ni2+ removal was fitted very well with the Freundlich model in terms of height correlation coefficient (R2), while Pb2+ was best fitted with Langmuir model for IRA 402-DR 23, the Cu2+ removal is described by the Langmuir model, and Cd2+, Ni2+ and Pb2+ removal was found to be in concordance with the Freundlich model for XAD7HP-DR 23. The M2+ elution from the chelate resins was carried out using 2 M HCl. The greater M2+ recovery from chelating resins mass confirmed their sustainability. The chelate resins used before and after M2+ removal by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis were evaluated.

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Section: Uv-vis Determination Of Dr 23mentioning

confidence: 99%

New Chelate Resins Prepared with Direct Red 23 for Cd2+, Ni2+, Cu2+ and Pb2+ Removal

et al. 2022

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“…Therefore, the need to develop new ecological and efficient resins for the removal of heavy metal ions from wastewater will always be in the interest of technological researchers. To obtain a chelating resin, a symbiosis between the resin matrix and the functionalization agents is required [ 26 ]. Moreover, the presence of aromatic rings of the chelating agents and the resin structure based on styrene-divinylbenzene is a promising symbiosis for obtaining new chelating materials through adsorption studies [ 27 , 28 , 29 ].…”

Section: Introductionmentioning

confidence: 99%

Preparation of Eco-Friendly Chelating Resins and Their Applications for Water Treatment

et al. 2023

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In the present study, two chelating resins were prepared and used for simultaneous adsorption of toxic metal ions, i.e., Cr3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, and Pb2+ (MX+). In the first step, chelating resins were prepared starting with styrene-divinylbenzene resin, a strong basic anion exchanger Amberlite IRA 402(Cl−) with two chelating agents, i.e., tartrazine (TAR) and amido black 10B (AB 10B). Key parameters such as contact time, pH, initial concentration, and stability were evaluated for the obtained chelating resins (IRA 402/TAR and IRA 402/AB 10B). The obtained chelating resins show excellent stability in 2M HCl, 2M NaOH, and also in ethanol (EtOH) medium. The stability of the chelating resins decreased when the combined mixture (2M HCl:EtOH = 2:1) was added. The above-mentioned aspect was more evident for IRA 402/TAR compared to IRA 402/AB 10B. Taking into account the higher stability of the IRA 402/TAR and IRA 402/AB 10B resins, in a second step, adsorption studies were carried out on complex acid effluents polluted with MX+. The adsorption of MX+ from an acidic aqueous medium on the chelating resins was evaluated using the ICP-MS method. The following affinity series under competitive analysis for IRA 402/TAR was obtained: Fe3+(44 µg/g) > Ni2+(39.8 µg/g) > Cd2+(34 µg/g) > Cr3+(33.2 µg/g) > Pb2+(32.7 µg/g) > Cu2+ (32.5 µg/g) > Mn2+(31 µg/g) > Co2+(29 µg/g) > Zn2+ (27.5 µg/g). While for IRA 402/AB 10B, the following behavior was observed: Fe3+(58 µg/g) > Ni2+(43.5 µg/g) > Cd2+(43 µg/g) > Cu2+(38 µg/g) > Cr3+(35 µg/g) > Pb2+(34.5 µg/g) > Co2+(32.8 µg/g) > Mn2+(33 µg/g) > Zn2+(32 µg/g), consistent with the decreasing affinity of MX+ for chelate resin. The chelating resins were characterized using TG, FTIR, and SEM analysis. The obtained results showed that the chelating resins prepared have promising potential for wastewater treatment in the context of the circular economy approach.

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“…Recently, Nicoleta Mirela Marin [ 48 ] developed natural and acrylic polymers with diazo acid Blue 11 (AB 113) as a chelating reagent to selectively remove metal ions; Zn 2+ , Mn 2+ , and Cr 3+ from acid polluted wastewater.…”

Section: Introductionmentioning

confidence: 99%

Development of Azo Dye Immobilized Poly (Glycidyl Methacrylate-Co-Methyl Methacrylate) Polymers Composites as Novel Adsorbents for Water Treatment Applications: Methylene Blue-Polymers Composites

et al. 2022

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Methylene blue azo dye (MB) immobilized onto Poly (glycidyl methacrylate-Co-methyl methacrylate), (PGMA-co-PMMA), and sulphonated Poly (glycidyl methacrylate-Co-methyl methacrylate), (SPGMA-co-PMMA), polymers composites have been developed as novel adsorbents for water treatment applications. The effect of copolymer composition and sulphonation on the MB content has been studied. Maximum MB content was correlated to the Polyglycidyl methacrylate content for both native and sulphonated copolymers. Furthermore, the effect of the adsorption conditions on the MB content was studied. Sulfonated Poly (glycidyl methacrylate; SPGMA) was the most efficient formed composite with the highest MB content. The developed composites’ chemical structure and morphology were characterized using characterization tools such as particle size, FTIR, TGA, and SEM analyses. The developed MB-SPGMA composite adsorbent (27 mg/g), for the first time, was tested for the removal of Cr (VI) ions and Mn (VII) metal ions from dichromate and permanganate contaminated waters under mild adsorption conditions, opening a new field of multiuse of the same adsorbent in the removal of more than one contaminants.

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Natural and Synthetic Polymers Modified with Acid Blue 113 for Removal of Cr3+, Zn2+ and Mn2+

Cited by 11 publications

References 35 publications

New Chelate Resins Prepared with Direct Red 23 for Cd2+, Ni2+, Cu2+ and Pb2+ Removal

New Chelate Resins Prepared with Direct Red 23 for Cd2+, Ni2+, Cu2+ and Pb2+ Removal

Preparation of Eco-Friendly Chelating Resins and Their Applications for Water Treatment

Development of Azo Dye Immobilized Poly (Glycidyl Methacrylate-Co-Methyl Methacrylate) Polymers Composites as Novel Adsorbents for Water Treatment Applications: Methylene Blue-Polymers Composites

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