Natural convection in air over a heated section-triangular roof with a fixed aspect ratio of 0.1 is experimentally investigated. The development of the flow over the roof subject to a range of temperatures is measured by digital interferometry and thermocouples. The experiments present distinct images of the thermal boundary layer, which changes from a quasi-steady to an unsteady state as the surface temperature of the triangular roof increases. Contrary to numerical simulations previously published, the observed flow becomes unsteady, which is very likely influenced by uncontrolled perturbations at the critical Rayleigh number where a pitchfork bifurcation of a steady flow is theoretically expected.