1 Sal'nikov's chemical reaction is very simple; it consists of two consecutive first-order steps, producing a product B from a precursor P via an active intermediate A, in P → A → B. The first step is assumed to be thermoneutral, with zero activation energy, whilst the second step is exothermic and has a positive activation energy. These properties make this mechanism one of the simplest to display thermokinetic oscillations, as seen in cool flames. We consider a pure gas, P, undergoing Sal'nikov's reaction in a closed spherical vessel, whose walls are held at a constant temperature. Natural convection becomes significant once the temperature is high enough for the Rayleigh